1,3-Alternate and C-1,2-Alternate Tetrahomodioxacalix[4]crowns. Crystal Structures and Metal Ion Complexation

K. No; Hye J. Chung; Hyun J. Yu; Seung H. Yang; Kwan H. Noh; P. Thuéry; J. Vicens; Jong S. Kim

doi:10.1023/A:1025672102973

1,3-Alternate and C-1,2-Alternate Tetrahomodioxacalix[4]crowns. Crystal Structures and Metal Ion Complexation

K. No, Hye J. Chung, Hyun J. Yu, Seung H. Yang, Kwan H. Noh, P. Thuéry, J. Vicens, Jong S. Kim

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Two novel tetrahomodioxacalix[4]crowns with crown-5 and crown-6 rings were synthesized. From X-ray crystal structures, homooxacalix[4]crown-5 (3) and homooxacalix[4]crown-6 (2) were found to be in the 1,3-alternate and the C-1,2-alternate conformations, respectively. Homooxacalix[4]crown-5 (1) shows a marked selectivity for cesium ion over other metal ions tested.

Original language	English
Pages (from-to)	97-103
Number of pages	7
Journal	Journal of Inclusion Phenomena
Volume	46
Issue number	1-2
DOIs	https://doi.org/10.1023/A:1025672102973
Publication status	Published - 2003 Jun
Externally published	Yes

Keywords

Calixarene
Complexation
Homooxacalixarene
X-ray crystal structure

ASJC Scopus subject areas

Food Science
Chemistry(all)
Condensed Matter Physics

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10.1023/A:1025672102973

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@article{6f3aed1519d94fcf835eac6f9f9aa5ab,

title = "1,3-Alternate and C-1,2-Alternate Tetrahomodioxacalix[4]crowns. Crystal Structures and Metal Ion Complexation",

abstract = "Two novel tetrahomodioxacalix[4]crowns with crown-5 and crown-6 rings were synthesized. From X-ray crystal structures, homooxacalix[4]crown-5 (3) and homooxacalix[4]crown-6 (2) were found to be in the 1,3-alternate and the C-1,2-alternate conformations, respectively. Homooxacalix[4]crown-5 (1) shows a marked selectivity for cesium ion over other metal ions tested.",

keywords = "Calixarene, Complexation, Homooxacalixarene, X-ray crystal structure",

author = "K. No and Chung, {Hye J.} and Yu, {Hyun J.} and Yang, {Seung H.} and Noh, {Kwan H.} and P. Thu{\'e}ry and J. Vicens and Kim, {Jong S.}",

note = "Funding Information: This research was supported by a Grant from the International Collaboration Project of Korea-France (KOSEF-ARIEL). We also gratefully thank KBSI in Daejon for the instrumentation support (1H and 13C NMR).",

year = "2003",

month = jun,

doi = "10.1023/A:1025672102973",

language = "English",

volume = "46",

pages = "97--103",

journal = "Journal of Inclusion Phenomena and Macrocyclic Chemistry",

issn = "1388-3127",

publisher = "Kluwer Academic Publishers",

number = "1-2",

}

TY - JOUR

T1 - 1,3-Alternate and C-1,2-Alternate Tetrahomodioxacalix[4]crowns. Crystal Structures and Metal Ion Complexation

AU - No, K.

AU - Chung, Hye J.

AU - Yu, Hyun J.

AU - Yang, Seung H.

AU - Noh, Kwan H.

AU - Thuéry, P.

AU - Vicens, J.

AU - Kim, Jong S.

N1 - Funding Information: This research was supported by a Grant from the International Collaboration Project of Korea-France (KOSEF-ARIEL). We also gratefully thank KBSI in Daejon for the instrumentation support (1H and 13C NMR).

PY - 2003/6

Y1 - 2003/6

N2 - Two novel tetrahomodioxacalix[4]crowns with crown-5 and crown-6 rings were synthesized. From X-ray crystal structures, homooxacalix[4]crown-5 (3) and homooxacalix[4]crown-6 (2) were found to be in the 1,3-alternate and the C-1,2-alternate conformations, respectively. Homooxacalix[4]crown-5 (1) shows a marked selectivity for cesium ion over other metal ions tested.

AB - Two novel tetrahomodioxacalix[4]crowns with crown-5 and crown-6 rings were synthesized. From X-ray crystal structures, homooxacalix[4]crown-5 (3) and homooxacalix[4]crown-6 (2) were found to be in the 1,3-alternate and the C-1,2-alternate conformations, respectively. Homooxacalix[4]crown-5 (1) shows a marked selectivity for cesium ion over other metal ions tested.

KW - Calixarene

KW - Complexation

KW - Homooxacalixarene

KW - X-ray crystal structure

UR - http://www.scopus.com/inward/record.url?scp=1642424275&partnerID=8YFLogxK

U2 - 10.1023/A:1025672102973

DO - 10.1023/A:1025672102973

M3 - Article

AN - SCOPUS:1642424275

SN - 1388-3127

VL - 46

SP - 97

EP - 103

JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

IS - 1-2

ER -

1,3-Alternate and C-1,2-Alternate Tetrahomodioxacalix[4]crowns. Crystal Structures and Metal Ion Complexation

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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