1,3-Diketone-Mediated Synthesis of Symmetrical Aryl Imides from Activated Amides

Myeong Seong Park, Karthik Rajan Rajamanickam, Kwang Ho Song, Sunwoo Lee

Research output: Contribution to journalArticlepeer-review

Abstract

Symmetrical aryl imides are synthesized from the reaction of activated amides such as N-phenyl-N-tosyl benzamides. The amine source is provided by lithium hexamethyldisilazide (LiHMDS), and a 1,3-diketone mediates the generation of the N-acyl donor from N,N-bis(trimethylsilyl)amide. Various symmetrical aryl amides are thus formed in moderate to good yields.

Original languageEnglish
Article numbere202300469
JournalAsian Journal of Organic Chemistry
Volume12
Issue number12
DOIs
Publication statusPublished - 2023 Dec

Bibliographical note

Publisher Copyright:
© 2023 Wiley-VCH GmbH.

Keywords

  • 1,3-diketone
  • amide
  • imide
  • lithium hexamethyldisilane
  • transamidation

ASJC Scopus subject areas

  • Organic Chemistry

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