A chiral pentadecanuclear metallamacrocycle with a sextuple twisted möbius topology

Rohith P. John; Mira Park; Dohyun Moon; Kyungjin Lee; Seunghee Hong; Yang Zou; Seop Hong Chang; Soo Lah Myoung

doi:10.1021/ja075945w

A chiral pentadecanuclear metallamacrocycle with a sextuple twisted möbius topology

Rohith P. John, Mira Park, Dohyun Moon, Kyungjin Lee, Seunghee Hong, Yang Zou, Seop Hong Chang, Soo Lah Myoung

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

66 Citations (Scopus)

Abstract

A C₃ symmetric pentadecanuclear metallamacrocycle was obtained by the self-assembly of a pentadentate bridging ligand, N-phenylpropiolyl salicylhydrazide (H₃L), and a manganese ion. The combination of a narrow Cα-Cβ region near the bridging domain and a bulky phenyl end away from the bridging domain as a steric domain induced clockwise twists in the cycle. The resulting macrocycle with a sextuple twisted Möbius topology was stabilized by extensive weak intramolecular interactions.

Original language	English
Pages (from-to)	14142-14143
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	46
DOIs	https://doi.org/10.1021/ja075945w
Publication status	Published - 2007 Nov 21

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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title = "A chiral pentadecanuclear metallamacrocycle with a sextuple twisted m{\"o}bius topology",

abstract = "A C3 symmetric pentadecanuclear metallamacrocycle was obtained by the self-assembly of a pentadentate bridging ligand, N-phenylpropiolyl salicylhydrazide (H3L), and a manganese ion. The combination of a narrow Cα-Cβ region near the bridging domain and a bulky phenyl end away from the bridging domain as a steric domain induced clockwise twists in the cycle. The resulting macrocycle with a sextuple twisted M{\"o}bius topology was stabilized by extensive weak intramolecular interactions.",

author = "John, {Rohith P.} and Mira Park and Dohyun Moon and Kyungjin Lee and Seunghee Hong and Yang Zou and Chang, {Seop Hong} and Myoung, {Soo Lah}",

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T1 - A chiral pentadecanuclear metallamacrocycle with a sextuple twisted möbius topology

AU - John, Rohith P.

AU - Park, Mira

AU - Moon, Dohyun

AU - Lee, Kyungjin

AU - Hong, Seunghee

AU - Zou, Yang

AU - Chang, Seop Hong

AU - Myoung, Soo Lah

PY - 2007/11/21

Y1 - 2007/11/21

N2 - A C3 symmetric pentadecanuclear metallamacrocycle was obtained by the self-assembly of a pentadentate bridging ligand, N-phenylpropiolyl salicylhydrazide (H3L), and a manganese ion. The combination of a narrow Cα-Cβ region near the bridging domain and a bulky phenyl end away from the bridging domain as a steric domain induced clockwise twists in the cycle. The resulting macrocycle with a sextuple twisted Möbius topology was stabilized by extensive weak intramolecular interactions.

AB - A C3 symmetric pentadecanuclear metallamacrocycle was obtained by the self-assembly of a pentadentate bridging ligand, N-phenylpropiolyl salicylhydrazide (H3L), and a manganese ion. The combination of a narrow Cα-Cβ region near the bridging domain and a bulky phenyl end away from the bridging domain as a steric domain induced clockwise twists in the cycle. The resulting macrocycle with a sextuple twisted Möbius topology was stabilized by extensive weak intramolecular interactions.

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U2 - 10.1021/ja075945w

DO - 10.1021/ja075945w

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AN - SCOPUS:36448937498

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EP - 14143

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 46

ER -

A chiral pentadecanuclear metallamacrocycle with a sextuple twisted möbius topology

Abstract

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