A dual channel fluorescence chemosensor for anions involving intermolecular excited state proton transfer

Kihang Choi; Andrew D. Hamilton

doi:10.1002/1521-3773(20011015)40:20<3912::AID-ANIE3912>3.0.CO;2-R

A dual channel fluorescence chemosensor for anions involving intermolecular excited state proton transfer

Kihang Choi, Andrew D. Hamilton

Research output: Contribution to journal › Article › peer-review

93 Citations (Scopus)

Abstract

A macrocycle containing an aminocoumarin fluorophore showed two different fluorescence emission bands on binding with certain anions. Proton transfer from the fluorophore excited state occurred depending on the basicity of the bound anion (see scheme, A^-: anion) and this new pathway makes more-sensitive anion sensing possible.

Original language	English
Pages (from-to)	3912-3915
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	20
DOIs	https://doi.org/10.1002/1521-3773(20011015)40:20<3912::AID-ANIE3912>3.0.CO;2-R
Publication status	Published - 2001 Oct 15
Externally published	Yes

Keywords

Anions
Host-guest systems
Molecular recognition
Sensors

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/1521-3773(20011015)40:20<3912::AID-ANIE3912>3.0.CO;2-R

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abstract = "A macrocycle containing an aminocoumarin fluorophore showed two different fluorescence emission bands on binding with certain anions. Proton transfer from the fluorophore excited state occurred depending on the basicity of the bound anion (see scheme, A-: anion) and this new pathway makes more-sensitive anion sensing possible.",

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AU - Hamilton, Andrew D.

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N2 - A macrocycle containing an aminocoumarin fluorophore showed two different fluorescence emission bands on binding with certain anions. Proton transfer from the fluorophore excited state occurred depending on the basicity of the bound anion (see scheme, A-: anion) and this new pathway makes more-sensitive anion sensing possible.

AB - A macrocycle containing an aminocoumarin fluorophore showed two different fluorescence emission bands on binding with certain anions. Proton transfer from the fluorophore excited state occurred depending on the basicity of the bound anion (see scheme, A-: anion) and this new pathway makes more-sensitive anion sensing possible.

KW - Anions

KW - Host-guest systems

KW - Molecular recognition

KW - Sensors

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DO - 10.1002/1521-3773(20011015)40:20<3912::AID-ANIE3912>3.0.CO;2-R

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A dual channel fluorescence chemosensor for anions involving intermolecular excited state proton transfer

Abstract

Keywords

ASJC Scopus subject areas

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