A Highly Reactive Functional Model for the Catechol Dioxygenases. Structure and Properties of [Fe(TPA)DBC]BPh₄

Keyphrases

• Activation Mechanism 50%
• Am(III) 50%
• Bond Energy 50%
• Carboxymethylation 50%
• Catechol 50%
• Catechol Dioxygenase 100%
• Catecholate 100%
• Covalency 100%
• Dianion 50%
• Fast Kinetics 50%
• Fe(III) 50%
• First-order Conditions 50%
• Functional Model 100%
• Glycine 50%
• High Conversion 50%
• High Reactivity 50%
• High Specificity 50%
• Kinetic Study 50%
• Lewis Acidity 50%
• Low Energy 50%
• Metal Catecholates 50%
• Order of Magnitude 50%
• Oxidative Cleavage 50%
• Percentage Yield 50%
• Proton 50%
• Pseudo-first Order 50%
• Semiquinone 100%
• Substantial Evidence 50%
• Substrate Activation 50%
• Tert 50%
• Three-order 50%
• Tris(2-pyridylmethyl)amine 50%

Pharmacology, Toxicology and Pharmaceutical Science

• Catechol 100%
• Catechol Derivative 50%
• Dioxygenase 100%
• Semiquinone 100%
• Trometamol 50%

Chemistry

• Lewis acidity 33%