A naphthalimide-calixarene as a two-faced and highly selective fluorescent chemosensor for Cu2+ or F-

Zhaochao Xu; Suki Kim; Ha Na Kim; Su Jung Han; Chongmok Lee; Jong Seung Kim; Xuhong Qian; Juyoung Yoon

doi:10.1016/j.tetlet.2007.10.109

A naphthalimide-calixarene as a two-faced and highly selective fluorescent chemosensor for Cu²⁺ or F^-

Zhaochao Xu
, Suki Kim
, Ha Na Kim
, Su Jung Han
, Chongmok Lee
, Jong Seung Kim
, Xuhong Qian^*
, Juyoung Yoon

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

111 Citations (Scopus)

Abstract

A new naphthalimide-calix[4]arene was synthesized as a two-faced and highly selective fluorescent chemosensor for Cu²⁺ or F^-. This chemosensor displayed a selective fluorescence quenching effect only with Cu²⁺ among the various metal ions. On the other hand, among the various anions, the title chemosensor displayed a selective fluorescence quenching effect only with F^-. The binding mode with F^- was further investigated using fluorescence changes and ¹H NMR experiments.

Original language	English
Pages (from-to)	9151-9154
Number of pages	4
Journal	Tetrahedron Letters
Volume	48
Issue number	52
DOIs	https://doi.org/10.1016/j.tetlet.2007.10.109
Publication status	Published - 2007 Dec 24

Bibliographical note

Funding Information:
This work was supported by the Korea Science and Engineering Foundation (KOSEF) grant funded by the Korean government (MOST) (NRL; R04-2007-000-2007-0), the Basic Science Research of KOSEF (R01-2006-000-10001-0), and BK21.

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/j.tetlet.2007.10.109

Cite this

@article{c97e7c2e8fef43ac9b729d14a610f027,

title = "A naphthalimide-calixarene as a two-faced and highly selective fluorescent chemosensor for Cu2+ or F-",

abstract = "A new naphthalimide-calix[4]arene was synthesized as a two-faced and highly selective fluorescent chemosensor for Cu2+ or F-. This chemosensor displayed a selective fluorescence quenching effect only with Cu2+ among the various metal ions. On the other hand, among the various anions, the title chemosensor displayed a selective fluorescence quenching effect only with F-. The binding mode with F- was further investigated using fluorescence changes and 1H NMR experiments.",

author = "Zhaochao Xu and Suki Kim and Kim, \{Ha Na\} and Han, \{Su Jung\} and Chongmok Lee and Kim, \{Jong Seung\} and Xuhong Qian and Juyoung Yoon",

note = "Funding Information: This work was supported by the Korea Science and Engineering Foundation (KOSEF) grant funded by the Korean government (MOST) (NRL; R04-2007-000-2007-0), the Basic Science Research of KOSEF (R01-2006-000-10001-0), and BK21. ",

year = "2007",

month = dec,

day = "24",

doi = "10.1016/j.tetlet.2007.10.109",

language = "English",

volume = "48",

pages = "9151--9154",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd",

number = "52",

}

TY - JOUR

T1 - A naphthalimide-calixarene as a two-faced and highly selective fluorescent chemosensor for Cu2+ or F-

AU - Xu, Zhaochao

AU - Kim, Suki

AU - Kim, Ha Na

AU - Han, Su Jung

AU - Lee, Chongmok

AU - Kim, Jong Seung

AU - Qian, Xuhong

AU - Yoon, Juyoung

N1 - Funding Information: This work was supported by the Korea Science and Engineering Foundation (KOSEF) grant funded by the Korean government (MOST) (NRL; R04-2007-000-2007-0), the Basic Science Research of KOSEF (R01-2006-000-10001-0), and BK21.

PY - 2007/12/24

Y1 - 2007/12/24

N2 - A new naphthalimide-calix[4]arene was synthesized as a two-faced and highly selective fluorescent chemosensor for Cu2+ or F-. This chemosensor displayed a selective fluorescence quenching effect only with Cu2+ among the various metal ions. On the other hand, among the various anions, the title chemosensor displayed a selective fluorescence quenching effect only with F-. The binding mode with F- was further investigated using fluorescence changes and 1H NMR experiments.

AB - A new naphthalimide-calix[4]arene was synthesized as a two-faced and highly selective fluorescent chemosensor for Cu2+ or F-. This chemosensor displayed a selective fluorescence quenching effect only with Cu2+ among the various metal ions. On the other hand, among the various anions, the title chemosensor displayed a selective fluorescence quenching effect only with F-. The binding mode with F- was further investigated using fluorescence changes and 1H NMR experiments.

UR - https://www.scopus.com/pages/publications/36448980981

U2 - 10.1016/j.tetlet.2007.10.109

DO - 10.1016/j.tetlet.2007.10.109

M3 - Article

AN - SCOPUS:36448980981

SN - 0040-4039

VL - 48

SP - 9151

EP - 9154

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 52

ER -