A new phosphorescent chemosensor bearing Zn-DPA sites for H 2PO4-

Hye Bin Kim; Yifan Liu; Dayoung Nam; Yinan Li; Sungnam Park; Juyoung Yoon; Myung Ho Hyun

doi:10.1016/j.dyepig.2014.02.015

A new phosphorescent chemosensor bearing Zn-DPA sites for H ₂PO₄^-

Hye Bin Kim, Yifan Liu, Dayoung Nam, Yinan Li, Sungnam Park, Juyoung Yoon, Myung Ho Hyun

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

A phosphorescence chemosensor bearing an iridium (III) complex as a communicating source and two Zn-DPA units acting as a preorganized binding site for H₂PO₄^- is presented. The phosphorescent chemosensor displayed a selective phosphorescence enhancement with H ₂PO₄^- in aqueous solution and at neutral pH. On the other hand, F^-, Cl^-, Br^-, I^-, NO₃^-, CH₃COO^-, and ClO ₄^- did not induce significant changes in phosphorescence. Furthermore, the phosphorescent chemosensor shows selectivity for H ₂PO₄^- over the related phosphate species, such as ATP and pyrophosphate. In addition, there was a distinct lifetime change only for H₂PO₄^-. The association constant was calculated to be 9.68 × 10⁴ M^-1 for H ₂PO₄^-.

Original language	English
Pages (from-to)	20-24
Number of pages	5
Journal	Dyes and Pigments
Volume	106
DOIs	https://doi.org/10.1016/j.dyepig.2014.02.015
Publication status	Published - 2014 Jul

Bibliographical note

Funding Information:
This research was supported by a grant from the National Research Foundation of Korea (NRF) funded by the Korean government (MSIP) (No. 2012-0002571 for M.H.H., No. 2010-0020209 for S.P. and National Creative Research Initiative : No. 2012R1A3A2048814 for J.Y.)

Keywords

Anion recognition
Dihydrogen phosphate sensing
Iridium complex
Phosphate sensor
Phosphorescence chemosensor
Zinc complex

ASJC Scopus subject areas

Chemical Engineering(all)
Process Chemistry and Technology

Access to Document

10.1016/j.dyepig.2014.02.015

Cite this

@article{4b52106a571f4781a9d1bedfe62a9619,

title = "A new phosphorescent chemosensor bearing Zn-DPA sites for H 2PO4-",

abstract = "A phosphorescence chemosensor bearing an iridium (III) complex as a communicating source and two Zn-DPA units acting as a preorganized binding site for H2PO4- is presented. The phosphorescent chemosensor displayed a selective phosphorescence enhancement with H 2PO4- in aqueous solution and at neutral pH. On the other hand, F-, Cl-, Br-, I-, NO3-, CH3COO-, and ClO 4- did not induce significant changes in phosphorescence. Furthermore, the phosphorescent chemosensor shows selectivity for H 2PO4- over the related phosphate species, such as ATP and pyrophosphate. In addition, there was a distinct lifetime change only for H2PO4-. The association constant was calculated to be 9.68 × 104 M-1 for H 2PO4-.",

keywords = "Anion recognition, Dihydrogen phosphate sensing, Iridium complex, Phosphate sensor, Phosphorescence chemosensor, Zinc complex",

author = "Kim, {Hye Bin} and Yifan Liu and Dayoung Nam and Yinan Li and Sungnam Park and Juyoung Yoon and Hyun, {Myung Ho}",

note = "Funding Information: This research was supported by a grant from the National Research Foundation of Korea (NRF) funded by the Korean government (MSIP) (No. 2012-0002571 for M.H.H., No. 2010-0020209 for S.P. and National Creative Research Initiative : No. 2012R1A3A2048814 for J.Y.) ",

year = "2014",

month = jul,

doi = "10.1016/j.dyepig.2014.02.015",

language = "English",

volume = "106",

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journal = "Dyes and Pigments",

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publisher = "Elsevier BV",

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T1 - A new phosphorescent chemosensor bearing Zn-DPA sites for H 2PO4-

AU - Kim, Hye Bin

AU - Liu, Yifan

AU - Nam, Dayoung

AU - Li, Yinan

AU - Park, Sungnam

AU - Yoon, Juyoung

AU - Hyun, Myung Ho

N1 - Funding Information: This research was supported by a grant from the National Research Foundation of Korea (NRF) funded by the Korean government (MSIP) (No. 2012-0002571 for M.H.H., No. 2010-0020209 for S.P. and National Creative Research Initiative : No. 2012R1A3A2048814 for J.Y.)

PY - 2014/7

Y1 - 2014/7

N2 - A phosphorescence chemosensor bearing an iridium (III) complex as a communicating source and two Zn-DPA units acting as a preorganized binding site for H2PO4- is presented. The phosphorescent chemosensor displayed a selective phosphorescence enhancement with H 2PO4- in aqueous solution and at neutral pH. On the other hand, F-, Cl-, Br-, I-, NO3-, CH3COO-, and ClO 4- did not induce significant changes in phosphorescence. Furthermore, the phosphorescent chemosensor shows selectivity for H 2PO4- over the related phosphate species, such as ATP and pyrophosphate. In addition, there was a distinct lifetime change only for H2PO4-. The association constant was calculated to be 9.68 × 104 M-1 for H 2PO4-.

AB - A phosphorescence chemosensor bearing an iridium (III) complex as a communicating source and two Zn-DPA units acting as a preorganized binding site for H2PO4- is presented. The phosphorescent chemosensor displayed a selective phosphorescence enhancement with H 2PO4- in aqueous solution and at neutral pH. On the other hand, F-, Cl-, Br-, I-, NO3-, CH3COO-, and ClO 4- did not induce significant changes in phosphorescence. Furthermore, the phosphorescent chemosensor shows selectivity for H 2PO4- over the related phosphate species, such as ATP and pyrophosphate. In addition, there was a distinct lifetime change only for H2PO4-. The association constant was calculated to be 9.68 × 104 M-1 for H 2PO4-.

KW - Anion recognition

KW - Dihydrogen phosphate sensing

KW - Iridium complex

KW - Phosphate sensor

KW - Phosphorescence chemosensor

KW - Zinc complex

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