A Thermodynamic Modelling of the Stability of Sigma Phase in the Cr-Fe-Ni-V High-Entropy Alloy System

Won Mi Choi; Yong Hee Jo; Dong Geun Kim; Seok Su Sohn; Sunghak Lee; Byeong Joo Lee

doi:10.1007/s11669-018-0672-x

A Thermodynamic Modelling of the Stability of Sigma Phase in the Cr-Fe-Ni-V High-Entropy Alloy System

Won Mi Choi, Yong Hee Jo, Dong Geun Kim, Seok Su Sohn, Sunghak Lee, Byeong Joo Lee

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

The addition of vanadium (V) to the representative Co-Cr-Fe-Mn-Ni high-entropy alloy (HEA) system is attracting attention expecting a large solid solution hardening effect. For the design of V-added HEAs, prediction of the sigma (σ) phase formation has been mainly issued because it affects a significant influence on the mechanical properties. Although the CALculation of PHAse Diagram (CALPHAD) approach can be a good tool for prediction of phase structures, robust thermodynamic database is still required for an accurate prediction of V-added HEA systems. The present work aims at providing a thermodynamic description for the Cr-Fe-Ni-V HEA system, focusing on the thermodynamic stability of the σ phase. A parameterization technique which minimizes the number of fitting parameter and simplifies the extension into higher-order systems is proposed and applied to the σ phase with multiple sublattice during modelling the Cr-Ni-V and Fe-Ni-V systems. The reliability of the developed thermodynamic description for the Cr-Fe-Ni-V quaternary system is experimentally confirmed by designing, fabricating and analysing the phase structures of a series of Cr-Fe-Ni-V HEAs.

Original language	English
Pages (from-to)	694-701
Number of pages	8
Journal	Journal of Phase Equilibria and Diffusion
Volume	39
Issue number	5
DOIs	https://doi.org/10.1007/s11669-018-0672-x
Publication status	Published - 2018 Oct 1
Externally published	Yes

Keywords

CALPHAD
Cr-Fe-Ni-V
high-entropy alloy
sigma phase
thermodynamic modelling

ASJC Scopus subject areas

Condensed Matter Physics
Metals and Alloys
Materials Chemistry

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10.1007/s11669-018-0672-x

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title = "A Thermodynamic Modelling of the Stability of Sigma Phase in the Cr-Fe-Ni-V High-Entropy Alloy System",

abstract = "The addition of vanadium (V) to the representative Co-Cr-Fe-Mn-Ni high-entropy alloy (HEA) system is attracting attention expecting a large solid solution hardening effect. For the design of V-added HEAs, prediction of the sigma (σ) phase formation has been mainly issued because it affects a significant influence on the mechanical properties. Although the CALculation of PHAse Diagram (CALPHAD) approach can be a good tool for prediction of phase structures, robust thermodynamic database is still required for an accurate prediction of V-added HEA systems. The present work aims at providing a thermodynamic description for the Cr-Fe-Ni-V HEA system, focusing on the thermodynamic stability of the σ phase. A parameterization technique which minimizes the number of fitting parameter and simplifies the extension into higher-order systems is proposed and applied to the σ phase with multiple sublattice during modelling the Cr-Ni-V and Fe-Ni-V systems. The reliability of the developed thermodynamic description for the Cr-Fe-Ni-V quaternary system is experimentally confirmed by designing, fabricating and analysing the phase structures of a series of Cr-Fe-Ni-V HEAs.",

keywords = "CALPHAD, Cr-Fe-Ni-V, high-entropy alloy, sigma phase, thermodynamic modelling",

author = "Choi, {Won Mi} and Jo, {Yong Hee} and Kim, {Dong Geun} and Sohn, {Seok Su} and Sunghak Lee and Lee, {Byeong Joo}",

note = "Funding Information: This research was supported by the Future Material Discovery Program of the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT of Korea (2016M3D1A1023383). This invited article is part of a special issue of the Journal of Phase Equilibria and Diffusion in honor of Prof. Zhanpeng Jin{\textquoteright}s 80th birthday. The special issue was organized by Prof. Ji-Cheng (JC) Zhao, The Ohio State University; Dr. Qing Chen, Thermo-Calc Software AB; and Prof. Yong Du, Central South University. Funding Information: Acknowledgments This research was supported by the Future Material Discovery Program of the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT of Korea (2016M3D1A1023383). Publisher Copyright: {\textcopyright} 2018, ASM International.",

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doi = "10.1007/s11669-018-0672-x",

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AU - Sohn, Seok Su

AU - Lee, Sunghak

AU - Lee, Byeong Joo

N1 - Funding Information: This research was supported by the Future Material Discovery Program of the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT of Korea (2016M3D1A1023383). This invited article is part of a special issue of the Journal of Phase Equilibria and Diffusion in honor of Prof. Zhanpeng Jin’s 80th birthday. The special issue was organized by Prof. Ji-Cheng (JC) Zhao, The Ohio State University; Dr. Qing Chen, Thermo-Calc Software AB; and Prof. Yong Du, Central South University. Funding Information: Acknowledgments This research was supported by the Future Material Discovery Program of the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT of Korea (2016M3D1A1023383). Publisher Copyright: © 2018, ASM International.

PY - 2018/10/1

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N2 - The addition of vanadium (V) to the representative Co-Cr-Fe-Mn-Ni high-entropy alloy (HEA) system is attracting attention expecting a large solid solution hardening effect. For the design of V-added HEAs, prediction of the sigma (σ) phase formation has been mainly issued because it affects a significant influence on the mechanical properties. Although the CALculation of PHAse Diagram (CALPHAD) approach can be a good tool for prediction of phase structures, robust thermodynamic database is still required for an accurate prediction of V-added HEA systems. The present work aims at providing a thermodynamic description for the Cr-Fe-Ni-V HEA system, focusing on the thermodynamic stability of the σ phase. A parameterization technique which minimizes the number of fitting parameter and simplifies the extension into higher-order systems is proposed and applied to the σ phase with multiple sublattice during modelling the Cr-Ni-V and Fe-Ni-V systems. The reliability of the developed thermodynamic description for the Cr-Fe-Ni-V quaternary system is experimentally confirmed by designing, fabricating and analysing the phase structures of a series of Cr-Fe-Ni-V HEAs.

AB - The addition of vanadium (V) to the representative Co-Cr-Fe-Mn-Ni high-entropy alloy (HEA) system is attracting attention expecting a large solid solution hardening effect. For the design of V-added HEAs, prediction of the sigma (σ) phase formation has been mainly issued because it affects a significant influence on the mechanical properties. Although the CALculation of PHAse Diagram (CALPHAD) approach can be a good tool for prediction of phase structures, robust thermodynamic database is still required for an accurate prediction of V-added HEA systems. The present work aims at providing a thermodynamic description for the Cr-Fe-Ni-V HEA system, focusing on the thermodynamic stability of the σ phase. A parameterization technique which minimizes the number of fitting parameter and simplifies the extension into higher-order systems is proposed and applied to the σ phase with multiple sublattice during modelling the Cr-Ni-V and Fe-Ni-V systems. The reliability of the developed thermodynamic description for the Cr-Fe-Ni-V quaternary system is experimentally confirmed by designing, fabricating and analysing the phase structures of a series of Cr-Fe-Ni-V HEAs.

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ER -

A Thermodynamic Modelling of the Stability of Sigma Phase in the Cr-Fe-Ni-V High-Entropy Alloy System

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Keywords

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