A two-photon excited luminescence of water-soluble rhodamine-platinum(II) complex: Fluorescent probe specific for Hg2+ detection in live cell

Jun Feng Zhang; Chang Su Lim; Bong-Rae Cho; Jong Seung Kim

doi:10.1016/j.talanta.2010.10.016

A two-photon excited luminescence of water-soluble rhodamine-platinum(II) complex: Fluorescent probe specific for Hg²⁺ detection in live cell

Jun Feng Zhang, Chang Su Lim, Bong-Rae Cho, Jong Seung Kim

Research output: Contribution to journal › Article › peer-review

74 Citations (Scopus)

Abstract

The first example of cyclometalated platinum(II)-containing rhodamine probe (1) with two-photon induced luminescent properties was synthesized and investigated for mercury detection. A highly selective color change of 1, from light yellow to pink, is observed only in the presence of Hg²⁺ due to the formation of 1,3,4-oxadiazole ring in 2. This selectivity of Hg ²⁺ with color changes can be observed easily by the naked-eye. Meanwhile, a remarkable turn-on and selective 20-fold fluorescent enhancement of 1 upon binding with Hg²⁺ over the other tested metal ions was observed. The water-soluble probe 1 was successfully applied in the visualizing of the site of Hg²⁺ accumulation as well as estimating of trace amounts of mercury ions in live HeLa cells by two-photon microscopy.

Original language	English
Pages (from-to)	658-662
Number of pages	5
Journal	Talanta
Volume	83
Issue number	2
DOIs	https://doi.org/10.1016/j.talanta.2010.10.016
Publication status	Published - 2010 Dec 15

Bibliographical note

Funding Information:
This work was supported by the CRI project (2010-0000728) (J.S. Kim), NRF grant ( R0A-2010-0018921 ), and Priority Research Centers Program through the NRF funded by the Ministry of Education, Science and Technology (No. 2010-0020209 ) (B.R. Cho). J.F. Zhang acknowledges the “ChunHui Project” Foundation of ministry of education of China , the Foundation of Department of Education of Yunnan Province of China ( 08Y0137 ) and the Foundation of Department of Science and Technology of Yunnan Province of China ( 2008CD104 ). CSL was supported by a BK21 scholarship.

Keywords

Platinum(II) complex
Rhodamine
Two-photon miscroscopy

ASJC Scopus subject areas

Analytical Chemistry

Access to Document

10.1016/j.talanta.2010.10.016

Cite this

@article{012b4d1963cd480b9973b3cbed805fe7,

title = "A two-photon excited luminescence of water-soluble rhodamine-platinum(II) complex: Fluorescent probe specific for Hg2+ detection in live cell",

abstract = "The first example of cyclometalated platinum(II)-containing rhodamine probe (1) with two-photon induced luminescent properties was synthesized and investigated for mercury detection. A highly selective color change of 1, from light yellow to pink, is observed only in the presence of Hg2+ due to the formation of 1,3,4-oxadiazole ring in 2. This selectivity of Hg 2+ with color changes can be observed easily by the naked-eye. Meanwhile, a remarkable turn-on and selective 20-fold fluorescent enhancement of 1 upon binding with Hg2+ over the other tested metal ions was observed. The water-soluble probe 1 was successfully applied in the visualizing of the site of Hg2+ accumulation as well as estimating of trace amounts of mercury ions in live HeLa cells by two-photon microscopy.",

keywords = "Platinum(II) complex, Rhodamine, Two-photon miscroscopy",

author = "Zhang, {Jun Feng} and Lim, {Chang Su} and Bong-Rae Cho and Kim, {Jong Seung}",

note = "Funding Information: This work was supported by the CRI project (2010-0000728) (J.S. Kim), NRF grant ( R0A-2010-0018921 ), and Priority Research Centers Program through the NRF funded by the Ministry of Education, Science and Technology (No. 2010-0020209 ) (B.R. Cho). J.F. Zhang acknowledges the “ChunHui Project” Foundation of ministry of education of China , the Foundation of Department of Education of Yunnan Province of China ( 08Y0137 ) and the Foundation of Department of Science and Technology of Yunnan Province of China ( 2008CD104 ). CSL was supported by a BK21 scholarship. ",

year = "2010",

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doi = "10.1016/j.talanta.2010.10.016",

language = "English",

volume = "83",

pages = "658--662",

journal = "Talanta",

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AU - Lim, Chang Su

AU - Cho, Bong-Rae

AU - Kim, Jong Seung

N1 - Funding Information: This work was supported by the CRI project (2010-0000728) (J.S. Kim), NRF grant ( R0A-2010-0018921 ), and Priority Research Centers Program through the NRF funded by the Ministry of Education, Science and Technology (No. 2010-0020209 ) (B.R. Cho). J.F. Zhang acknowledges the “ChunHui Project” Foundation of ministry of education of China , the Foundation of Department of Education of Yunnan Province of China ( 08Y0137 ) and the Foundation of Department of Science and Technology of Yunnan Province of China ( 2008CD104 ). CSL was supported by a BK21 scholarship.

PY - 2010/12/15

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