TY - JOUR
T1 - Ag-incorporated macroporous CeO2 catalysts for soot oxidation
T2 - Effects of Ag amount on the generation of active oxygen species
AU - Lee, Jae Hwan
AU - Lee, Seong Ho
AU - Choung, Jin Woo
AU - Kim, Chang Hwan
AU - Lee, Kwan Young
N1 - Funding Information:
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (NRF-2016R1A5A1009592).
PY - 2019/6/5
Y1 - 2019/6/5
N2 - A series of CeO2-based catalysts were investigated for soot oxidation with O2. The macroporous CeO2 catalyst (M-CeO2) showed higher soot oxidation activity than mesoporous CeO2 due to the enhanced contact between catalyst and soot caused by the large pore size of M-CeO2. Moreover, various amounts of Ag (2–20 wt.%) were introduced to M-CeO2 to increase the activity, and the Ag-incorporated macroporous CeO2 catalysts (Ag(x)_M-CeO2) were characterized. Raman spectra showed that the ratio of active oxygen species (Oxn−) were different according to amount of Ag. The ratio of highly reactive superoxide (O2−) was largest for the Ag(5)_M-CeO2 catalyst, and then it was decreased as the Ag amount increased further. In addition, XPS analysis showed that the difference in Oxn− generation could be attributed to diverse surface oxygen vacancies in the catalysts. Hence, the amount of loaded Ag affected the surface oxygen vacancies of Ag(x)_M-CeO2 and consequently the ratio of Oxn− was different according to the surface oxygen vacancies of the catalysts. Ag(5)_M-CeO2 with the appropriate surface oxygen vacancies induced the promotion of O2− generation, resulting in the best soot oxidation activity. It was concluded that the amount of Ag on CeO2 has a great influence on the catalytic soot oxidation activity, and proper surface oxygen vacancies facilitated O2− generation, whereas excessive surface oxygen vacancies hindered the formation of highly reactive Oxn−.
AB - A series of CeO2-based catalysts were investigated for soot oxidation with O2. The macroporous CeO2 catalyst (M-CeO2) showed higher soot oxidation activity than mesoporous CeO2 due to the enhanced contact between catalyst and soot caused by the large pore size of M-CeO2. Moreover, various amounts of Ag (2–20 wt.%) were introduced to M-CeO2 to increase the activity, and the Ag-incorporated macroporous CeO2 catalysts (Ag(x)_M-CeO2) were characterized. Raman spectra showed that the ratio of active oxygen species (Oxn−) were different according to amount of Ag. The ratio of highly reactive superoxide (O2−) was largest for the Ag(5)_M-CeO2 catalyst, and then it was decreased as the Ag amount increased further. In addition, XPS analysis showed that the difference in Oxn− generation could be attributed to diverse surface oxygen vacancies in the catalysts. Hence, the amount of loaded Ag affected the surface oxygen vacancies of Ag(x)_M-CeO2 and consequently the ratio of Oxn− was different according to the surface oxygen vacancies of the catalysts. Ag(5)_M-CeO2 with the appropriate surface oxygen vacancies induced the promotion of O2− generation, resulting in the best soot oxidation activity. It was concluded that the amount of Ag on CeO2 has a great influence on the catalytic soot oxidation activity, and proper surface oxygen vacancies facilitated O2− generation, whereas excessive surface oxygen vacancies hindered the formation of highly reactive Oxn−.
KW - Active oxygen species
KW - Ag-loaded CeO
KW - Macroporous structure
KW - Soot oxidation
KW - Surface oxygen vacancies
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U2 - 10.1016/j.apcatb.2019.01.064
DO - 10.1016/j.apcatb.2019.01.064
M3 - Article
AN - SCOPUS:85061055659
SN - 0926-3373
VL - 246
SP - 356
EP - 366
JO - Applied Catalysis B: Environmental
JF - Applied Catalysis B: Environmental
ER -