Al-doped Ni-rich cathode powders prepared from the precursor powders with fine size and spherical shape

S. H. Ju; H. C. Jang; Y. C. Kang

doi:10.1016/j.electacta.2007.05.064

Al-doped Ni-rich cathode powders prepared from the precursor powders with fine size and spherical shape

S. H. Ju, H. C. Jang, Y. C. Kang

Research output: Contribution to journal › Article › peer-review

84 Citations (Scopus)

Abstract

LiNi_0.8Co_0.15Al_0.05O₂ cathode powders with fine size and spherical shape were prepared by solid-state reaction method using the Ni-Co-Al-O precursor powders with fine size and spherical shape. The Ni-Co-Al-O precursor powders with fine size and filled inner structure were prepared by spray pyrolysis from the spray solution with drying control chemical additive (DCCA), citric acid and ethylene glycol. The one LiNi_0.8Co_0.15Al_0.05O₂ cathode powder with fine size and spherical shape was formed from the one precursor powder with spherical shape and filled morphology. The mean size of the spherical shape LiNi_0.8Co_0.15Al_0.05O₂ cathode powders was 1.1 μm. The initial discharge capacity of the LiNi_0.8Co_0.15Al_0.05O₂ cathode powders prepared from the spray solution with citric acid, ethylene glycol and DCCA was 200 mAh g^-1. The cycle properties of the cathode powders prepared from the spray solution with and without additives were compared.

Original language	English
Pages (from-to)	7286-7292
Number of pages	7
Journal	Electrochimica Acta
Volume	52
Issue number	25
DOIs	https://doi.org/10.1016/j.electacta.2007.05.064
Publication status	Published - 2007 Sept
Externally published	Yes

Keywords

Cathode materials
Electrochemical properties
Lithium nicklate
Lithium secondary battery
Spray pyrolysis

ASJC Scopus subject areas

General Chemical Engineering
Electrochemistry

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10.1016/j.electacta.2007.05.064

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title = "Al-doped Ni-rich cathode powders prepared from the precursor powders with fine size and spherical shape",

abstract = "LiNi0.8Co0.15Al0.05O2 cathode powders with fine size and spherical shape were prepared by solid-state reaction method using the Ni-Co-Al-O precursor powders with fine size and spherical shape. The Ni-Co-Al-O precursor powders with fine size and filled inner structure were prepared by spray pyrolysis from the spray solution with drying control chemical additive (DCCA), citric acid and ethylene glycol. The one LiNi0.8Co0.15Al0.05O2 cathode powder with fine size and spherical shape was formed from the one precursor powder with spherical shape and filled morphology. The mean size of the spherical shape LiNi0.8Co0.15Al0.05O2 cathode powders was 1.1 μm. The initial discharge capacity of the LiNi0.8Co0.15Al0.05O2 cathode powders prepared from the spray solution with citric acid, ethylene glycol and DCCA was 200 mAh g-1. The cycle properties of the cathode powders prepared from the spray solution with and without additives were compared.",

keywords = "Cathode materials, Electrochemical properties, Lithium nicklate, Lithium secondary battery, Spray pyrolysis",

author = "Ju, {S. H.} and Jang, {H. C.} and Kang, {Y. C.}",

year = "2007",

month = sep,

doi = "10.1016/j.electacta.2007.05.064",

language = "English",

volume = "52",

pages = "7286--7292",

journal = "Electrochimica Acta",

issn = "0013-4686",

publisher = "Elsevier Ltd",

number = "25",

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TY - JOUR

T1 - Al-doped Ni-rich cathode powders prepared from the precursor powders with fine size and spherical shape

AU - Ju, S. H.

AU - Jang, H. C.

AU - Kang, Y. C.

PY - 2007/9

Y1 - 2007/9

N2 - LiNi0.8Co0.15Al0.05O2 cathode powders with fine size and spherical shape were prepared by solid-state reaction method using the Ni-Co-Al-O precursor powders with fine size and spherical shape. The Ni-Co-Al-O precursor powders with fine size and filled inner structure were prepared by spray pyrolysis from the spray solution with drying control chemical additive (DCCA), citric acid and ethylene glycol. The one LiNi0.8Co0.15Al0.05O2 cathode powder with fine size and spherical shape was formed from the one precursor powder with spherical shape and filled morphology. The mean size of the spherical shape LiNi0.8Co0.15Al0.05O2 cathode powders was 1.1 μm. The initial discharge capacity of the LiNi0.8Co0.15Al0.05O2 cathode powders prepared from the spray solution with citric acid, ethylene glycol and DCCA was 200 mAh g-1. The cycle properties of the cathode powders prepared from the spray solution with and without additives were compared.

AB - LiNi0.8Co0.15Al0.05O2 cathode powders with fine size and spherical shape were prepared by solid-state reaction method using the Ni-Co-Al-O precursor powders with fine size and spherical shape. The Ni-Co-Al-O precursor powders with fine size and filled inner structure were prepared by spray pyrolysis from the spray solution with drying control chemical additive (DCCA), citric acid and ethylene glycol. The one LiNi0.8Co0.15Al0.05O2 cathode powder with fine size and spherical shape was formed from the one precursor powder with spherical shape and filled morphology. The mean size of the spherical shape LiNi0.8Co0.15Al0.05O2 cathode powders was 1.1 μm. The initial discharge capacity of the LiNi0.8Co0.15Al0.05O2 cathode powders prepared from the spray solution with citric acid, ethylene glycol and DCCA was 200 mAh g-1. The cycle properties of the cathode powders prepared from the spray solution with and without additives were compared.

KW - Cathode materials

KW - Electrochemical properties

KW - Lithium nicklate

KW - Lithium secondary battery

KW - Spray pyrolysis

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M3 - Article

AN - SCOPUS:34547553200

SN - 0013-4686

VL - 52

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EP - 7292

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 25

ER -

Al-doped Ni-rich cathode powders prepared from the precursor powders with fine size and spherical shape

Abstract

Keywords

ASJC Scopus subject areas

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