Aminoindanol-based chiral derivatizing agents for the determination of the absolute configuration of carboxylic acids

Minjung Park; Seon Mi Kim; Kihang Choi

doi:10.1039/c2ob26168e

Aminoindanol-based chiral derivatizing agents for the determination of the absolute configuration of carboxylic acids

Minjung Park
, Seon Mi Kim
, Kihang Choi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

New chiral derivatizing agents have been prepared through a simple, short-step synthesis. The absolute configuration of α-chiral carboxylic acids can be assigned on the basis of the NMR chemical shift difference between diastereomeric esters. Because of the modular structures of the agents, the anisotropic effect could be easily manipulated to afford large chemical shift differences even in polar solvents.

Original language	English
Pages (from-to)	8051-8054
Number of pages	4
Journal	Organic and Biomolecular Chemistry
Volume	10
Issue number	40
DOIs	https://doi.org/10.1039/c2ob26168e
Publication status	Published - 2012 Oct 28

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1039/c2ob26168e

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abstract = "New chiral derivatizing agents have been prepared through a simple, short-step synthesis. The absolute configuration of α-chiral carboxylic acids can be assigned on the basis of the NMR chemical shift difference between diastereomeric esters. Because of the modular structures of the agents, the anisotropic effect could be easily manipulated to afford large chemical shift differences even in polar solvents.",

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AU - Park, Minjung

AU - Kim, Seon Mi

AU - Choi, Kihang

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Y1 - 2012/10/28

N2 - New chiral derivatizing agents have been prepared through a simple, short-step synthesis. The absolute configuration of α-chiral carboxylic acids can be assigned on the basis of the NMR chemical shift difference between diastereomeric esters. Because of the modular structures of the agents, the anisotropic effect could be easily manipulated to afford large chemical shift differences even in polar solvents.

AB - New chiral derivatizing agents have been prepared through a simple, short-step synthesis. The absolute configuration of α-chiral carboxylic acids can be assigned on the basis of the NMR chemical shift difference between diastereomeric esters. Because of the modular structures of the agents, the anisotropic effect could be easily manipulated to afford large chemical shift differences even in polar solvents.

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AN - SCOPUS:84866949747

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IS - 40

ER -

Aminoindanol-based chiral derivatizing agents for the determination of the absolute configuration of carboxylic acids

Abstract

ASJC Scopus subject areas

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