TY - JOUR
T1 - An assessment of HOx chemistry in the tropical pacific boundary layer
T2 - Comparison of model simulations with observations recorded during PEM tropics A
AU - Chen, G.
AU - Davis, D.
AU - Crawford, J.
AU - Heikes, B.
AU - O'Sullivan, D.
AU - Lee, M.
AU - Eisele, F.
AU - Mauldin, L.
AU - Tanner, D.
AU - Collins, J.
AU - Barrick, J.
AU - Anderson, B.
AU - Blake, D.
AU - Bradshaw, J.
AU - Sandholm, S.
AU - Carroll, M.
AU - Albercook, G.
AU - Clarke, A.
PY - 2001
Y1 - 2001
N2 - Reported are the results from a comparison of OH, H2O2CH3OOH, and O3 observations with model predictions based on current HOx-CH4 reaction mechanisms. The field observations are those recorded during the NASA GTE field program, PEM-Tropics A. The major focus of this paper is on those data generated on the NASA P-3B aircraft during a mission flown in the marine boundary layer (MBL) near Christmas Island, a site located in the centra l equatorial Pacific (i.e., 2°N, 157°W). Taking advantage of the stability of the southeastern trade-winds, an air parcel was sampled in a Lagrangian mode over a significant fraction of a solar day. Analyses of these data revealed excellent agreement between model simulated and observed OH. In addition, the model simulations reproduced the major features in the observed diurnal profiles of H2O2 and CH3OOH. In the case of O3, the model captured the key observational feature which involved an early morning maximum. An examination of the MBL HOx budget indicated that the O(1D) + H2O reaction is the major source of HOx while the major sinks involve both physical and chemical processes involving the peroxide species, H2O2 and CH3OOH. Overall, the generally good agreement between model and observations suggests that our current understanding of HOx-CH4 chemistry in the tropical MBL is quite good; however, there remains a need to critically examine this chemistry when both CH2O and HO2 are added to the species measured.
AB - Reported are the results from a comparison of OH, H2O2CH3OOH, and O3 observations with model predictions based on current HOx-CH4 reaction mechanisms. The field observations are those recorded during the NASA GTE field program, PEM-Tropics A. The major focus of this paper is on those data generated on the NASA P-3B aircraft during a mission flown in the marine boundary layer (MBL) near Christmas Island, a site located in the centra l equatorial Pacific (i.e., 2°N, 157°W). Taking advantage of the stability of the southeastern trade-winds, an air parcel was sampled in a Lagrangian mode over a significant fraction of a solar day. Analyses of these data revealed excellent agreement between model simulated and observed OH. In addition, the model simulations reproduced the major features in the observed diurnal profiles of H2O2 and CH3OOH. In the case of O3, the model captured the key observational feature which involved an early morning maximum. An examination of the MBL HOx budget indicated that the O(1D) + H2O reaction is the major source of HOx while the major sinks involve both physical and chemical processes involving the peroxide species, H2O2 and CH3OOH. Overall, the generally good agreement between model and observations suggests that our current understanding of HOx-CH4 chemistry in the tropical MBL is quite good; however, there remains a need to critically examine this chemistry when both CH2O and HO2 are added to the species measured.
KW - Hydroxyl radical
KW - Marine boundary layer
KW - Peroxides
KW - Photochemistry
KW - Tropical Pacific
UR - http://www.scopus.com/inward/record.url?scp=0035058963&partnerID=8YFLogxK
U2 - 10.1023/A:1006402626288
DO - 10.1023/A:1006402626288
M3 - Article
AN - SCOPUS:0035058963
SN - 0167-7764
VL - 38
SP - 317
EP - 344
JO - Journal of Atmospheric Chemistry
JF - Journal of Atmospheric Chemistry
IS - 3
ER -