Analysis on the effect of operating conditions on electrochemical conversion of carbon dioxide to formic acid

Hak Yoon Kim; Insoo Choi; Sang Hyun Ahn; Seung Jun Hwang; Sung Jong Yoo; Jonghee Han; Jihyun Kim; Hansoo Park; Jong Hyun Jang; Soo Kil Kim

doi:10.1016/j.ijhydene.2014.03.145

Analysis on the effect of operating conditions on electrochemical conversion of carbon dioxide to formic acid

Hak Yoon Kim, Insoo Choi, Sang Hyun Ahn, Seung Jun Hwang, Sung Jong Yoo, Jonghee Han, Jihyun Kim, Hansoo Park, Jong Hyun Jang, Soo Kil Kim

Research output: Contribution to journal › Article › peer-review

80 Citations (Scopus)

Abstract

Electrochemical reduction of CO₂ to HCOOH was performed on a Sn electrode using a proton exchange membrane-embedded electrolysis cell. The effects of reaction conditions such as catholyte and anolyte types, reduction potential, catholyte pH, and reaction temperature on the amount of HCOOH and its faradaic efficiency were investigated. Four different electrolytes (KOH, KHCO₃, KCl, KHSO₄) were chosen as the candidate catholyte and anolyte; the most suitable electrolyte was chosen by monitoring the amount of HCOOH and faradaic efficiency. The effect of the pH of the selected catholyte on the conversion of CO₂ to HCOOH was also investigated. In addition, the reaction temperature was varied and its effect was studied. From the observations made, we determined the optimal reaction conditions for the production of HCOOH via the electrochemical reduction of CO₂ by a systematic approach.

Original language	English
Pages (from-to)	16506-16512
Number of pages	7
Journal	International Journal of Hydrogen Energy
Volume	39
Issue number	29
DOIs	https://doi.org/10.1016/j.ijhydene.2014.03.145
Publication status	Published - 2014 Oct 2

Bibliographical note

Funding Information:
This research was supported by a grant from the Korea CCS R&D Center (KCRC) funded by the Korea government ( Ministry of Science, ICT & Future Planning ) ( NRF-2013M1A8A1056298 ).

Publisher Copyright:
© 2014 Hydrogen Energy Publications, LLC.

Keywords

Carbon dioxide
Electrochemical conversion
Formic acid
Sn electrode

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Fuel Technology
Condensed Matter Physics
Energy Engineering and Power Technology

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.ijhydene.2014.03.145

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title = "Analysis on the effect of operating conditions on electrochemical conversion of carbon dioxide to formic acid",

abstract = "Electrochemical reduction of CO2 to HCOOH was performed on a Sn electrode using a proton exchange membrane-embedded electrolysis cell. The effects of reaction conditions such as catholyte and anolyte types, reduction potential, catholyte pH, and reaction temperature on the amount of HCOOH and its faradaic efficiency were investigated. Four different electrolytes (KOH, KHCO3, KCl, KHSO4) were chosen as the candidate catholyte and anolyte; the most suitable electrolyte was chosen by monitoring the amount of HCOOH and faradaic efficiency. The effect of the pH of the selected catholyte on the conversion of CO2 to HCOOH was also investigated. In addition, the reaction temperature was varied and its effect was studied. From the observations made, we determined the optimal reaction conditions for the production of HCOOH via the electrochemical reduction of CO2 by a systematic approach.",

keywords = "Carbon dioxide, Electrochemical conversion, Formic acid, Sn electrode",

author = "Kim, {Hak Yoon} and Insoo Choi and Ahn, {Sang Hyun} and Hwang, {Seung Jun} and Yoo, {Sung Jong} and Jonghee Han and Jihyun Kim and Hansoo Park and Jang, {Jong Hyun} and Kim, {Soo Kil}",

note = "Funding Information: This research was supported by a grant from the Korea CCS R&D Center (KCRC) funded by the Korea government ( Ministry of Science, ICT & Future Planning ) ( NRF-2013M1A8A1056298 ). Publisher Copyright: {\textcopyright} 2014 Hydrogen Energy Publications, LLC.",

year = "2014",

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doi = "10.1016/j.ijhydene.2014.03.145",

language = "English",

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T1 - Analysis on the effect of operating conditions on electrochemical conversion of carbon dioxide to formic acid

AU - Kim, Hak Yoon

AU - Choi, Insoo

AU - Ahn, Sang Hyun

AU - Hwang, Seung Jun

AU - Yoo, Sung Jong

AU - Han, Jonghee

AU - Kim, Jihyun

AU - Park, Hansoo

AU - Jang, Jong Hyun

AU - Kim, Soo Kil

N1 - Funding Information: This research was supported by a grant from the Korea CCS R&D Center (KCRC) funded by the Korea government ( Ministry of Science, ICT & Future Planning ) ( NRF-2013M1A8A1056298 ). Publisher Copyright: © 2014 Hydrogen Energy Publications, LLC.

PY - 2014/10/2

Y1 - 2014/10/2

N2 - Electrochemical reduction of CO2 to HCOOH was performed on a Sn electrode using a proton exchange membrane-embedded electrolysis cell. The effects of reaction conditions such as catholyte and anolyte types, reduction potential, catholyte pH, and reaction temperature on the amount of HCOOH and its faradaic efficiency were investigated. Four different electrolytes (KOH, KHCO3, KCl, KHSO4) were chosen as the candidate catholyte and anolyte; the most suitable electrolyte was chosen by monitoring the amount of HCOOH and faradaic efficiency. The effect of the pH of the selected catholyte on the conversion of CO2 to HCOOH was also investigated. In addition, the reaction temperature was varied and its effect was studied. From the observations made, we determined the optimal reaction conditions for the production of HCOOH via the electrochemical reduction of CO2 by a systematic approach.

AB - Electrochemical reduction of CO2 to HCOOH was performed on a Sn electrode using a proton exchange membrane-embedded electrolysis cell. The effects of reaction conditions such as catholyte and anolyte types, reduction potential, catholyte pH, and reaction temperature on the amount of HCOOH and its faradaic efficiency were investigated. Four different electrolytes (KOH, KHCO3, KCl, KHSO4) were chosen as the candidate catholyte and anolyte; the most suitable electrolyte was chosen by monitoring the amount of HCOOH and faradaic efficiency. The effect of the pH of the selected catholyte on the conversion of CO2 to HCOOH was also investigated. In addition, the reaction temperature was varied and its effect was studied. From the observations made, we determined the optimal reaction conditions for the production of HCOOH via the electrochemical reduction of CO2 by a systematic approach.

KW - Carbon dioxide

KW - Electrochemical conversion

KW - Formic acid

KW - Sn electrode

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M3 - Article

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VL - 39

SP - 16506

EP - 16512

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 29

ER -

Analysis on the effect of operating conditions on electrochemical conversion of carbon dioxide to formic acid

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

UN SDGs

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