Approach to the synthesis of nogalarol via the cycloaddition of a carbene-chromium complex with a functionalized alkyne

M. F. Semmelhack; Nakcheol Jeong

doi:10.1016/S0040-4039(00)94579-9

Approach to the synthesis of nogalarol via the cycloaddition of a carbene-chromium complex with a functionalized alkyne

M. F. Semmelhack, Nakcheol Jeong

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26 Citations (Scopus)

Abstract

The alkyne, 4, prepared stereoselectively in 7 steps from acetyl furan, reacts with (methoxy)(phenyl)carbenepentacarbonylchromium(0), 15, to give the model (16) for nogalarol (1b) in 43% yield.

Original language	English
Pages (from-to)	605-608
Number of pages	4
Journal	Tetrahedron Letters
Volume	31
Issue number	5
DOIs	https://doi.org/10.1016/S0040-4039(00)94579-9
Publication status	Published - 1990
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)94579-9

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title = "Approach to the synthesis of nogalarol via the cycloaddition of a carbene-chromium complex with a functionalized alkyne",

abstract = "The alkyne, 4, prepared stereoselectively in 7 steps from acetyl furan, reacts with (methoxy)(phenyl)carbenepentacarbonylchromium(0), 15, to give the model (16) for nogalarol (1b) in 43% yield.",

author = "Semmelhack, {M. F.} and Nakcheol Jeong",

year = "1990",

doi = "10.1016/S0040-4039(00)94579-9",

language = "English",

volume = "31",

pages = "605--608",

journal = "Tetrahedron Letters",

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T1 - Approach to the synthesis of nogalarol via the cycloaddition of a carbene-chromium complex with a functionalized alkyne

AU - Semmelhack, M. F.

AU - Jeong, Nakcheol

PY - 1990

Y1 - 1990

N2 - The alkyne, 4, prepared stereoselectively in 7 steps from acetyl furan, reacts with (methoxy)(phenyl)carbenepentacarbonylchromium(0), 15, to give the model (16) for nogalarol (1b) in 43% yield.

AB - The alkyne, 4, prepared stereoselectively in 7 steps from acetyl furan, reacts with (methoxy)(phenyl)carbenepentacarbonylchromium(0), 15, to give the model (16) for nogalarol (1b) in 43% yield.

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U2 - 10.1016/S0040-4039(00)94579-9

DO - 10.1016/S0040-4039(00)94579-9

M3 - Article

AN - SCOPUS:0025057506

SN - 0040-4039

VL - 31

SP - 605

EP - 608

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 5

ER -

Approach to the synthesis of nogalarol via the cycloaddition of a carbene-chromium complex with a functionalized alkyne

Abstract

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