Asymmetric Pauson-Khand-type reaction mediated by Rh(I) catalyst at ambient temperature

Eun Kim Dong; Su Kim In; Virginie Ratovelomanana-Vidal; Jean Pierre Genêt; Nakcheol Jeong

doi:10.1021/jo801236c

Asymmetric Pauson-Khand-type reaction mediated by Rh(I) catalyst at ambient temperature

Eun Kim Dong, Su Kim In, Virginie Ratovelomanana-Vidal, Jean Pierre Genêt, Nakcheol Jeong

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

(Chemical Equation Presented) An efficient asymmetric PKR mediated by Rh(I) catalyst at ambient temperature was developed. The reaction utilizing a Rh(I) catalyst bearing a (R)-3,5-diMeC₄H₄-BINAP ligand at 18-20°C under a reduced partial pressure of CO (0.1 atm) provided PKR products in high chemical yield as well as high enantioselectivity.

Original language	English
Pages (from-to)	7985-7989
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	73
Issue number	20
DOIs	https://doi.org/10.1021/jo801236c
Publication status	Published - 2008 Oct 17

ASJC Scopus subject areas

Organic Chemistry

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10.1021/jo801236c

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abstract = "(Chemical Equation Presented) An efficient asymmetric PKR mediated by Rh(I) catalyst at ambient temperature was developed. The reaction utilizing a Rh(I) catalyst bearing a (R)-3,5-diMeC4H4-BINAP ligand at 18-20°C under a reduced partial pressure of CO (0.1 atm) provided PKR products in high chemical yield as well as high enantioselectivity.",

author = "Dong, {Eun Kim} and In, {Su Kim} and Virginie Ratovelomanana-Vidal and Gen{\^e}t, {Jean Pierre} and Nakcheol Jeong",

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AU - Dong, Eun Kim

AU - In, Su Kim

AU - Ratovelomanana-Vidal, Virginie

AU - Genêt, Jean Pierre

AU - Jeong, Nakcheol

PY - 2008/10/17

Y1 - 2008/10/17

N2 - (Chemical Equation Presented) An efficient asymmetric PKR mediated by Rh(I) catalyst at ambient temperature was developed. The reaction utilizing a Rh(I) catalyst bearing a (R)-3,5-diMeC4H4-BINAP ligand at 18-20°C under a reduced partial pressure of CO (0.1 atm) provided PKR products in high chemical yield as well as high enantioselectivity.

AB - (Chemical Equation Presented) An efficient asymmetric PKR mediated by Rh(I) catalyst at ambient temperature was developed. The reaction utilizing a Rh(I) catalyst bearing a (R)-3,5-diMeC4H4-BINAP ligand at 18-20°C under a reduced partial pressure of CO (0.1 atm) provided PKR products in high chemical yield as well as high enantioselectivity.

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JO - Journal of Organic Chemistry

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ER -

Asymmetric Pauson-Khand-type reaction mediated by Rh(I) catalyst at ambient temperature

Abstract

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