Basic anion-exchange resin (AER)-supported Au-Pd alloy nanoparticles for the oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-furan dicarboxylic acid (FDCA)

Churchil A. Antonyraj; Nhan Thanh Thien Huynh; Seok Kyu Park; Seunghan Shin; Yong Jin Kim; Sangyong Kim; Kwan Young Lee; Jin Ku Cho

doi:10.1016/j.apcata.2017.09.012

Basic anion-exchange resin (AER)-supported Au-Pd alloy nanoparticles for the oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-furan dicarboxylic acid (FDCA)

Churchil A. Antonyraj, Nhan Thanh Thien Huynh, Seok Kyu Park, Seunghan Shin, Yong Jin Kim, Sangyong Kim, Kwan Young Lee, Jin Ku Cho

Research output: Contribution to journal › Article › peer-review

63 Citations (Scopus)

Abstract

Au-Pd alloy nanoparticles supported on basic anion-exchange resin (AER) have exceptional catalytic activity for the oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-furan dicarboxylic acid (FDCA) with an equimolar amount of base. SEM-EDX and TEM analyses show that 5–20 nm Au-Pd alloy nanoparticles are well dispersed both on the resin surface and inside resin spheres by a simple procedure without any assistance of additives. XPS analysis reveals that Au- and Pd metals exist in an alloy form on the AER support, which is confirmed by a comparison study with a mixture of AER-supported monometallic nanoparticles (AER-supported Au and AER-supported Pd). In the presence of a 1:1 ratio of Au-Pd alloy nanoparticles over Amberlite IRA-743 resin with O₂ (10 bar) at 373 K in an equimolar Na₂CO₃ aqueous solution, HMF is oxidized to FDCA with a 93.2% yield. On the other hand, mixture of AER-supported Au and AER-supported Pd affords only a 52% FDCA yield under identical conditions. This catalyst can be used 6 times without any significant loss of activity. FDCA is also obtained from HMF with an 82.9% yield in air (40 bar).

Original language	English
Pages (from-to)	230-236
Number of pages	7
Journal	Applied Catalysis A: General
Volume	547
DOIs	https://doi.org/10.1016/j.apcata.2017.09.012
Publication status	Published - 2017

Bibliographical note

Funding Information:
This work was financially supported by the National Research Council of Science & Technology (NST) grant by the Korea government (No. CAP-11-04-KIST ) and we acknowledge financial support for this research by the Internal Research Program ( PEO17250 & PJB17130 ) of Korea Institute of Industrial Technology (KITECH).

Publisher Copyright:
© 2017 Elsevier B.V.

Keywords

2,5-Furan dicarboxylic acid (FDCA)
5-Hydroxymethyl-2-furfural (HMF)
Anion-exchange resin (AER)
Au-Pd alloynanoparticles
Oxidation

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology

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10.1016/j.apcata.2017.09.012

Cite this

@article{c297fb194cfb4cc39c6f98e4f3c6a8ef,

title = "Basic anion-exchange resin (AER)-supported Au-Pd alloy nanoparticles for the oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-furan dicarboxylic acid (FDCA)",

abstract = "Au-Pd alloy nanoparticles supported on basic anion-exchange resin (AER) have exceptional catalytic activity for the oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-furan dicarboxylic acid (FDCA) with an equimolar amount of base. SEM-EDX and TEM analyses show that 5–20 nm Au-Pd alloy nanoparticles are well dispersed both on the resin surface and inside resin spheres by a simple procedure without any assistance of additives. XPS analysis reveals that Au- and Pd metals exist in an alloy form on the AER support, which is confirmed by a comparison study with a mixture of AER-supported monometallic nanoparticles (AER-supported Au and AER-supported Pd). In the presence of a 1:1 ratio of Au-Pd alloy nanoparticles over Amberlite IRA-743 resin with O2 (10 bar) at 373 K in an equimolar Na2CO3 aqueous solution, HMF is oxidized to FDCA with a 93.2% yield. On the other hand, mixture of AER-supported Au and AER-supported Pd affords only a 52% FDCA yield under identical conditions. This catalyst can be used 6 times without any significant loss of activity. FDCA is also obtained from HMF with an 82.9% yield in air (40 bar).",

keywords = "2,5-Furan dicarboxylic acid (FDCA), 5-Hydroxymethyl-2-furfural (HMF), Anion-exchange resin (AER), Au-Pd alloynanoparticles, Oxidation",

author = "Antonyraj, {Churchil A.} and Huynh, {Nhan Thanh Thien} and Park, {Seok Kyu} and Seunghan Shin and Kim, {Yong Jin} and Sangyong Kim and Lee, {Kwan Young} and Cho, {Jin Ku}",

note = "Funding Information: This work was financially supported by the National Research Council of Science & Technology (NST) grant by the Korea government (No. CAP-11-04-KIST ) and we acknowledge financial support for this research by the Internal Research Program ( PEO17250 & PJB17130 ) of Korea Institute of Industrial Technology (KITECH). Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",

year = "2017",

doi = "10.1016/j.apcata.2017.09.012",

language = "English",

volume = "547",

pages = "230--236",

journal = "Applied Catalysis A: General",

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T1 - Basic anion-exchange resin (AER)-supported Au-Pd alloy nanoparticles for the oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-furan dicarboxylic acid (FDCA)

AU - Antonyraj, Churchil A.

AU - Huynh, Nhan Thanh Thien

AU - Park, Seok Kyu

AU - Shin, Seunghan

AU - Kim, Yong Jin

AU - Kim, Sangyong

AU - Lee, Kwan Young

AU - Cho, Jin Ku

N1 - Funding Information: This work was financially supported by the National Research Council of Science & Technology (NST) grant by the Korea government (No. CAP-11-04-KIST ) and we acknowledge financial support for this research by the Internal Research Program ( PEO17250 & PJB17130 ) of Korea Institute of Industrial Technology (KITECH). Publisher Copyright: © 2017 Elsevier B.V.

PY - 2017

Y1 - 2017

N2 - Au-Pd alloy nanoparticles supported on basic anion-exchange resin (AER) have exceptional catalytic activity for the oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-furan dicarboxylic acid (FDCA) with an equimolar amount of base. SEM-EDX and TEM analyses show that 5–20 nm Au-Pd alloy nanoparticles are well dispersed both on the resin surface and inside resin spheres by a simple procedure without any assistance of additives. XPS analysis reveals that Au- and Pd metals exist in an alloy form on the AER support, which is confirmed by a comparison study with a mixture of AER-supported monometallic nanoparticles (AER-supported Au and AER-supported Pd). In the presence of a 1:1 ratio of Au-Pd alloy nanoparticles over Amberlite IRA-743 resin with O2 (10 bar) at 373 K in an equimolar Na2CO3 aqueous solution, HMF is oxidized to FDCA with a 93.2% yield. On the other hand, mixture of AER-supported Au and AER-supported Pd affords only a 52% FDCA yield under identical conditions. This catalyst can be used 6 times without any significant loss of activity. FDCA is also obtained from HMF with an 82.9% yield in air (40 bar).

AB - Au-Pd alloy nanoparticles supported on basic anion-exchange resin (AER) have exceptional catalytic activity for the oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-furan dicarboxylic acid (FDCA) with an equimolar amount of base. SEM-EDX and TEM analyses show that 5–20 nm Au-Pd alloy nanoparticles are well dispersed both on the resin surface and inside resin spheres by a simple procedure without any assistance of additives. XPS analysis reveals that Au- and Pd metals exist in an alloy form on the AER support, which is confirmed by a comparison study with a mixture of AER-supported monometallic nanoparticles (AER-supported Au and AER-supported Pd). In the presence of a 1:1 ratio of Au-Pd alloy nanoparticles over Amberlite IRA-743 resin with O2 (10 bar) at 373 K in an equimolar Na2CO3 aqueous solution, HMF is oxidized to FDCA with a 93.2% yield. On the other hand, mixture of AER-supported Au and AER-supported Pd affords only a 52% FDCA yield under identical conditions. This catalyst can be used 6 times without any significant loss of activity. FDCA is also obtained from HMF with an 82.9% yield in air (40 bar).

KW - 2,5-Furan dicarboxylic acid (FDCA)

KW - 5-Hydroxymethyl-2-furfural (HMF)

KW - Anion-exchange resin (AER)

KW - Au-Pd alloynanoparticles

KW - Oxidation

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U2 - 10.1016/j.apcata.2017.09.012

DO - 10.1016/j.apcata.2017.09.012

M3 - Article

AN - SCOPUS:85029287581

SN - 0926-860X

VL - 547

SP - 230

EP - 236

JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

ER -

Basic anion-exchange resin (AER)-supported Au-Pd alloy nanoparticles for the oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-furan dicarboxylic acid (FDCA)

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

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