Bifunctional nanoparticulated nickel ferrite thin films: Resistive memory and aqueous battery applications

Tukaram D. Dongale; Sagar S. Khot; Akshay A. Patil; Siddhesh V. Wagh; Prashant B. Patil; Deepak P. Dubal; Tae Geun Kim

doi:10.1016/j.matdes.2021.109493

Bifunctional nanoparticulated nickel ferrite thin films: Resistive memory and aqueous battery applications

Tukaram D. Dongale, Sagar S. Khot, Akshay A. Patil, Siddhesh V. Wagh, Prashant B. Patil, Deepak P. Dubal, Tae Geun Kim

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Herein, excellent non-volatile memory and aqueous battery properties of solution-processable nickel ferrite (NFO) nanomaterial were demonstrated. In the case of non-volatile memory property, the device operates on ±2 V resistive switching voltage and shows double valued charge-magnetic flux characteristics. Excellent endurance (10³) and retention (10⁴ s) non-volatile memory properties with a good memory window (10³) were observed for NFO memristive device. The conduction and resistive switching mechanisms based on experimental data are provided. Furthermore, the present work investigates the electrochemical performance of the NFO thin film electrode in the different electrolytes (viz. Na₂SO_4, Li₂SO₄, and Na₂SO₄: Li₂SO₄). It was revealed that the NFO thin film shows improved electrochemical performance in Na₂SO₄ electrolyte with a high specific capacity of 18.56 mAh/g at 1 mA/cm² current density. The electrochemical impedance spectroscopic results reveal that the NFO thin film electrode shows low series and charge transfer resistance values for Na₂SO₄ electrolyte than other electrolytes. The diffusion coefficient of different ions (D_Na+, D_Li+ and D_Na+:Li+) were found to be 9.975 × 10⁻¹⁰ cm² s⁻¹, 3.292 × 10⁻¹¹ cm² s⁻¹, 2 × 10⁻¹⁰ cm² s⁻¹, respectively.

Original language	English
Article number	109493
Journal	Materials and Design
Volume	201
DOIs	https://doi.org/10.1016/j.matdes.2021.109493
Publication status	Published - 2021 Mar

Bibliographical note

Publisher Copyright:
© 2021 The Authors

Keywords

Aqueous battery
Data storage materials
Energy storage materials
Memristive device
Nickel ferrite
Resistive switching

ASJC Scopus subject areas

General Materials Science
Mechanics of Materials
Mechanical Engineering

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10.1016/j.matdes.2021.109493

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title = "Bifunctional nanoparticulated nickel ferrite thin films: Resistive memory and aqueous battery applications",

abstract = "Herein, excellent non-volatile memory and aqueous battery properties of solution-processable nickel ferrite (NFO) nanomaterial were demonstrated. In the case of non-volatile memory property, the device operates on ±2 V resistive switching voltage and shows double valued charge-magnetic flux characteristics. Excellent endurance (103) and retention (104 s) non-volatile memory properties with a good memory window (103) were observed for NFO memristive device. The conduction and resistive switching mechanisms based on experimental data are provided. Furthermore, the present work investigates the electrochemical performance of the NFO thin film electrode in the different electrolytes (viz. Na2SO4, Li2SO4, and Na2SO4: Li2SO4). It was revealed that the NFO thin film shows improved electrochemical performance in Na2SO4 electrolyte with a high specific capacity of 18.56 mAh/g at 1 mA/cm2 current density. The electrochemical impedance spectroscopic results reveal that the NFO thin film electrode shows low series and charge transfer resistance values for Na2SO4 electrolyte than other electrolytes. The diffusion coefficient of different ions (DNa+, DLi+ and DNa+:Li+) were found to be 9.975 × 10−10 cm2 s−1, 3.292 × 10−11 cm2 s−1, 2 × 10−10 cm2 s−1, respectively.",

keywords = "Aqueous battery, Data storage materials, Energy storage materials, Memristive device, Nickel ferrite, Resistive switching",

author = "Dongale, {Tukaram D.} and Khot, {Sagar S.} and Patil, {Akshay A.} and Wagh, {Siddhesh V.} and Patil, {Prashant B.} and Dubal, {Deepak P.} and Kim, {Tae Geun}",

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doi = "10.1016/j.matdes.2021.109493",

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T2 - Resistive memory and aqueous battery applications

AU - Dongale, Tukaram D.

AU - Khot, Sagar S.

AU - Patil, Akshay A.

AU - Wagh, Siddhesh V.

AU - Patil, Prashant B.

AU - Dubal, Deepak P.

AU - Kim, Tae Geun

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N2 - Herein, excellent non-volatile memory and aqueous battery properties of solution-processable nickel ferrite (NFO) nanomaterial were demonstrated. In the case of non-volatile memory property, the device operates on ±2 V resistive switching voltage and shows double valued charge-magnetic flux characteristics. Excellent endurance (103) and retention (104 s) non-volatile memory properties with a good memory window (103) were observed for NFO memristive device. The conduction and resistive switching mechanisms based on experimental data are provided. Furthermore, the present work investigates the electrochemical performance of the NFO thin film electrode in the different electrolytes (viz. Na2SO4, Li2SO4, and Na2SO4: Li2SO4). It was revealed that the NFO thin film shows improved electrochemical performance in Na2SO4 electrolyte with a high specific capacity of 18.56 mAh/g at 1 mA/cm2 current density. The electrochemical impedance spectroscopic results reveal that the NFO thin film electrode shows low series and charge transfer resistance values for Na2SO4 electrolyte than other electrolytes. The diffusion coefficient of different ions (DNa+, DLi+ and DNa+:Li+) were found to be 9.975 × 10−10 cm2 s−1, 3.292 × 10−11 cm2 s−1, 2 × 10−10 cm2 s−1, respectively.

AB - Herein, excellent non-volatile memory and aqueous battery properties of solution-processable nickel ferrite (NFO) nanomaterial were demonstrated. In the case of non-volatile memory property, the device operates on ±2 V resistive switching voltage and shows double valued charge-magnetic flux characteristics. Excellent endurance (103) and retention (104 s) non-volatile memory properties with a good memory window (103) were observed for NFO memristive device. The conduction and resistive switching mechanisms based on experimental data are provided. Furthermore, the present work investigates the electrochemical performance of the NFO thin film electrode in the different electrolytes (viz. Na2SO4, Li2SO4, and Na2SO4: Li2SO4). It was revealed that the NFO thin film shows improved electrochemical performance in Na2SO4 electrolyte with a high specific capacity of 18.56 mAh/g at 1 mA/cm2 current density. The electrochemical impedance spectroscopic results reveal that the NFO thin film electrode shows low series and charge transfer resistance values for Na2SO4 electrolyte than other electrolytes. The diffusion coefficient of different ions (DNa+, DLi+ and DNa+:Li+) were found to be 9.975 × 10−10 cm2 s−1, 3.292 × 10−11 cm2 s−1, 2 × 10−10 cm2 s−1, respectively.

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KW - Data storage materials

KW - Energy storage materials

KW - Memristive device

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Bifunctional nanoparticulated nickel ferrite thin films: Resistive memory and aqueous battery applications

Abstract

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Keywords

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