BODIPY appended cone-calix[4]arene: selective fluorescence changes upon Ca2+ binding

Hyun Jung Kim; Jong Seung Kim

doi:10.1016/j.tetlet.2006.07.088

BODIPY appended cone-calix[4]arene: selective fluorescence changes upon Ca²⁺ binding

Hyun Jung Kim, Jong Seung Kim

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

BODIPY appended new calix[4]arene diethyl ester (1) has been synthesized in the cone conformation. With respect to fluorescence intensity changes upon metal ion complexation, 1 shows a Ca²⁺ ion selectivity over other metal cations. Presence of two proximal hydroxyl groups and two facing ethyl esters in BODIPY-calix[4]arene were observed to play an important role in exhibiting its selective Ca²⁺ ion binding.

Original language	English
Pages (from-to)	7051-7055
Number of pages	5
Journal	Tetrahedron Letters
Volume	47
Issue number	39
DOIs	https://doi.org/10.1016/j.tetlet.2006.07.088
Publication status	Published - 2006 Sept 25
Externally published	Yes

Keywords

Calixarenes
Fluorescence
Reverse PET

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/j.tetlet.2006.07.088

Cite this

@article{afc6cbd8b6d74cbeab16fa5502ff34a8,

title = "BODIPY appended cone-calix[4]arene: selective fluorescence changes upon Ca2+ binding",

abstract = "BODIPY appended new calix[4]arene diethyl ester (1) has been synthesized in the cone conformation. With respect to fluorescence intensity changes upon metal ion complexation, 1 shows a Ca2+ ion selectivity over other metal cations. Presence of two proximal hydroxyl groups and two facing ethyl esters in BODIPY-calix[4]arene were observed to play an important role in exhibiting its selective Ca2+ ion binding.",

keywords = "Calixarenes, Fluorescence, Reverse PET",

author = "Kim, {Hyun Jung} and Kim, {Jong Seung}",

year = "2006",

month = sep,

day = "25",

doi = "10.1016/j.tetlet.2006.07.088",

language = "English",

volume = "47",

pages = "7051--7055",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "39",

}

TY - JOUR

T1 - BODIPY appended cone-calix[4]arene

T2 - selective fluorescence changes upon Ca2+ binding

AU - Kim, Hyun Jung

AU - Kim, Jong Seung

PY - 2006/9/25

Y1 - 2006/9/25

N2 - BODIPY appended new calix[4]arene diethyl ester (1) has been synthesized in the cone conformation. With respect to fluorescence intensity changes upon metal ion complexation, 1 shows a Ca2+ ion selectivity over other metal cations. Presence of two proximal hydroxyl groups and two facing ethyl esters in BODIPY-calix[4]arene were observed to play an important role in exhibiting its selective Ca2+ ion binding.

AB - BODIPY appended new calix[4]arene diethyl ester (1) has been synthesized in the cone conformation. With respect to fluorescence intensity changes upon metal ion complexation, 1 shows a Ca2+ ion selectivity over other metal cations. Presence of two proximal hydroxyl groups and two facing ethyl esters in BODIPY-calix[4]arene were observed to play an important role in exhibiting its selective Ca2+ ion binding.

KW - Calixarenes

KW - Fluorescence

KW - Reverse PET

UR - http://www.scopus.com/inward/record.url?scp=33748906824&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33748906824&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2006.07.088

DO - 10.1016/j.tetlet.2006.07.088

M3 - Article

AN - SCOPUS:33748906824

SN - 0040-4039

VL - 47

SP - 7051

EP - 7055

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 39

ER -