Capture and detection of SO2 using a chemically stable Mg(ii)-MOF

Eva Martínez-Ahumada, Dae won Kim, Mohammad Wahiduzzaman, Paulina Carmona-Monroy, Alfredo López-Olvera, Daryl R. Williams, Vladimir Martis, Hugo A. Lara-García, S. López-Morales, Diego Solis-Ibarra, Guillaume Maurin, Ilich A. Ibarra, Chang Seop Hong

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

The MOF-type Mg2(dobpdc) shows a record high capacity for SO2 capture (19.5 mmol g−1 at 298 K and up to 1 bar), high chemical stability towards dry and humid SO2 and an outstanding cycling performance with facile regeneration. Advanced molecular simulations have been coupled to gain insight into the molecular mechanisms responsible for the high adsorption of SO2. Fluorescence experiments further demonstrated the SO2 detection properties of this MOF material.

Original languageEnglish
Pages (from-to)18636-18643
Number of pages8
JournalJournal of Materials Chemistry A
Volume10
Issue number36
DOIs
Publication statusPublished - 2022 Jul 26

Bibliographical note

Publisher Copyright:
© 2022 The Royal Society of Chemistry.

ASJC Scopus subject areas

  • General Chemistry
  • Renewable Energy, Sustainability and the Environment
  • General Materials Science

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