Catalytic pyrolysis of mandarin residue from the mandarin juice processing industry

Jeong Wook Kim; Sung Hoon Park; Jinho Jung; Jong Ki Jeon; Chang Hyun Ko; Kwang Eun Jeong; Young Kwon Park

doi:10.1016/j.biortech.2013.03.062

Catalytic pyrolysis of mandarin residue from the mandarin juice processing industry

Jeong Wook Kim, Sung Hoon Park, Jinho Jung, Jong Ki Jeon, Chang Hyun Ko, Kwang Eun Jeong, Young Kwon Park

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

In this study, the catalytic pyrolysis of mandarin residue from the mandarin juice processing industry was carried out using pyrolysis gas chromatography/mass spectroscopy and employing microporous zeolite catalysts, HZSM-5 (SiO₂/Al₂O₃=23 and 80) and HBeta (SiO₂/Al₂O₃=25). The effect of acidity of the catalyst was investigated by comparing the activity of two HZSM-5 catalysts with different SiO₂/Al₂O₃ ratios. The effect of catalyst structure was explored by comparing the results obtained using HZSM-5 (23) and HBeta. Most oxygenates produced from non-catalytic pyrolysis were removed by catalytic upgrading, whereas the yields of mono-aromatics, which are important feedstock materials for the chemical industry, increased considerably, improving the quality of the bio-oil produced. HZSM-5 (23), having the highest acidity among the catalysts used in this study, showed superior catalytic activity to those of HZSM-5 (80) and HBeta. Pt/HZSM-5 (23) and Ga/HZSM-5 (23) resulted in an even higher yield of aromatics.

Original language	English
Pages (from-to)	431-436
Number of pages	6
Journal	Bioresource technology
Volume	136
DOIs	https://doi.org/10.1016/j.biortech.2013.03.062
Publication status	Published - 2013 May

Bibliographical note

Funding Information:
This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (2012R1A1B3003394).

Keywords

Aromatics
Bio-oil
Catalytic pyrolysis
Mandarin residue
Metal

ASJC Scopus subject areas

Bioengineering
Environmental Engineering
Renewable Energy, Sustainability and the Environment
Waste Management and Disposal

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.biortech.2013.03.062

Cite this

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title = "Catalytic pyrolysis of mandarin residue from the mandarin juice processing industry",

abstract = "In this study, the catalytic pyrolysis of mandarin residue from the mandarin juice processing industry was carried out using pyrolysis gas chromatography/mass spectroscopy and employing microporous zeolite catalysts, HZSM-5 (SiO2/Al2O3=23 and 80) and HBeta (SiO2/Al2O3=25). The effect of acidity of the catalyst was investigated by comparing the activity of two HZSM-5 catalysts with different SiO2/Al2O3 ratios. The effect of catalyst structure was explored by comparing the results obtained using HZSM-5 (23) and HBeta. Most oxygenates produced from non-catalytic pyrolysis were removed by catalytic upgrading, whereas the yields of mono-aromatics, which are important feedstock materials for the chemical industry, increased considerably, improving the quality of the bio-oil produced. HZSM-5 (23), having the highest acidity among the catalysts used in this study, showed superior catalytic activity to those of HZSM-5 (80) and HBeta. Pt/HZSM-5 (23) and Ga/HZSM-5 (23) resulted in an even higher yield of aromatics.",

keywords = "Aromatics, Bio-oil, Catalytic pyrolysis, Mandarin residue, Metal",

author = "Kim, {Jeong Wook} and Park, {Sung Hoon} and Jinho Jung and Jeon, {Jong Ki} and Ko, {Chang Hyun} and Jeong, {Kwang Eun} and Park, {Young Kwon}",

note = "Funding Information: This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (2012R1A1B3003394). ",

year = "2013",

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doi = "10.1016/j.biortech.2013.03.062",

language = "English",

volume = "136",

pages = "431--436",

journal = "Bioresource technology",

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AU - Kim, Jeong Wook

AU - Park, Sung Hoon

AU - Jung, Jinho

AU - Jeon, Jong Ki

AU - Ko, Chang Hyun

AU - Jeong, Kwang Eun

AU - Park, Young Kwon

N1 - Funding Information: This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (2012R1A1B3003394).

PY - 2013/5

Y1 - 2013/5

N2 - In this study, the catalytic pyrolysis of mandarin residue from the mandarin juice processing industry was carried out using pyrolysis gas chromatography/mass spectroscopy and employing microporous zeolite catalysts, HZSM-5 (SiO2/Al2O3=23 and 80) and HBeta (SiO2/Al2O3=25). The effect of acidity of the catalyst was investigated by comparing the activity of two HZSM-5 catalysts with different SiO2/Al2O3 ratios. The effect of catalyst structure was explored by comparing the results obtained using HZSM-5 (23) and HBeta. Most oxygenates produced from non-catalytic pyrolysis were removed by catalytic upgrading, whereas the yields of mono-aromatics, which are important feedstock materials for the chemical industry, increased considerably, improving the quality of the bio-oil produced. HZSM-5 (23), having the highest acidity among the catalysts used in this study, showed superior catalytic activity to those of HZSM-5 (80) and HBeta. Pt/HZSM-5 (23) and Ga/HZSM-5 (23) resulted in an even higher yield of aromatics.

AB - In this study, the catalytic pyrolysis of mandarin residue from the mandarin juice processing industry was carried out using pyrolysis gas chromatography/mass spectroscopy and employing microporous zeolite catalysts, HZSM-5 (SiO2/Al2O3=23 and 80) and HBeta (SiO2/Al2O3=25). The effect of acidity of the catalyst was investigated by comparing the activity of two HZSM-5 catalysts with different SiO2/Al2O3 ratios. The effect of catalyst structure was explored by comparing the results obtained using HZSM-5 (23) and HBeta. Most oxygenates produced from non-catalytic pyrolysis were removed by catalytic upgrading, whereas the yields of mono-aromatics, which are important feedstock materials for the chemical industry, increased considerably, improving the quality of the bio-oil produced. HZSM-5 (23), having the highest acidity among the catalysts used in this study, showed superior catalytic activity to those of HZSM-5 (80) and HBeta. Pt/HZSM-5 (23) and Ga/HZSM-5 (23) resulted in an even higher yield of aromatics.

KW - Aromatics

KW - Bio-oil

KW - Catalytic pyrolysis

KW - Mandarin residue

KW - Metal

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Catalytic pyrolysis of mandarin residue from the mandarin juice processing industry

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

UN SDGs

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