Cavity-tailored, self-sorting supramolecular catalytic boxes for selective oxidation

Joong Lee Suk; So Hye Cho; Karen L. Mulfort; David M. Tiede; Joseph T. Hupp; Son Binh T. Nguyen

doi:10.1021/ja804014y

Cavity-tailored, self-sorting supramolecular catalytic boxes for selective oxidation

Joong Lee Suk, So Hye Cho, Karen L. Mulfort, David M. Tiede, Joseph T. Hupp, Son Binh T. Nguyen

Research output: Contribution to journal › Article › peer-review

151 Citations (Scopus)

Abstract

Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by solution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.

Original language	English
Pages (from-to)	16828-16829
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	50
DOIs	https://doi.org/10.1021/ja804014y
Publication status	Published - 2008 Dec 17
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja804014y

Cite this

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abstract = "Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by solution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.",

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AU - Suk, Joong Lee

AU - Cho, So Hye

AU - Mulfort, Karen L.

AU - Tiede, David M.

AU - Hupp, Joseph T.

AU - Nguyen, Son Binh T.

PY - 2008/12/17

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AB - Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by solution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.

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Cavity-tailored, self-sorting supramolecular catalytic boxes for selective oxidation

Abstract

ASJC Scopus subject areas

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