CCl4 decomposition by gliding arc plasma: Role of C2 compounds on products distribution

Antonius Indarto; Dae Ryook Yang; Jae Wook Choi; Hwaung Lee; Hyung Keun Song

doi:10.1080/00986440701293363

CCl₄ decomposition by gliding arc plasma: Role of C₂ compounds on products distribution

Antonius Indarto, Dae Ryook Yang, Jae Wook Choi, Hwaung Lee, Hyung Keun Song

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

The goal of this work is to investigate the role of existing C₂ compounds in the plasma reactions of carbon tetrachloride (CCl₄) decomposition. The experiment of CCl₄ decomposition was carried out by gliding arc plasma. The decomposition products were dominated by CO, CO₂, and Cl₂. The conversion of CCl₄ into Cl₂ and (CO + CO₂) reaches ∼50% and ∼40%, respectively. Other chlorinated compounds were suspected to be produced, such as COCl, COCl₂, and C₂ compounds. In order to prove the existence of those compounds, for example, chlorinated C₂ compounds, a kinetic simulation was performed and cross-checked with the experimental results to clarify the reactions mechanism.

Original language	English
Pages (from-to)	1111-1125
Number of pages	15
Journal	Chemical Engineering Communications
Volume	194
Issue number	8
DOIs	https://doi.org/10.1080/00986440701293363
Publication status	Published - 2007 Aug

Bibliographical note

Funding Information:
This study was supported by the National Research Laboratory Program of the Korea Ministry of Science and Technology.

Copyright:
Copyright 2008 Elsevier B.V., All rights reserved.

Keywords

CCl decomposition
Gliding arc
Plasma
Reaction mechanism

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

Access to Document

10.1080/00986440701293363

Cite this

@article{e3b3a8e877ed485499154b5660b442da,

title = "CCl4 decomposition by gliding arc plasma: Role of C2 compounds on products distribution",

abstract = "The goal of this work is to investigate the role of existing C2 compounds in the plasma reactions of carbon tetrachloride (CCl4) decomposition. The experiment of CCl4 decomposition was carried out by gliding arc plasma. The decomposition products were dominated by CO, CO2, and Cl2. The conversion of CCl4 into Cl2 and (CO + CO2) reaches ∼50% and ∼40%, respectively. Other chlorinated compounds were suspected to be produced, such as COCl, COCl2, and C2 compounds. In order to prove the existence of those compounds, for example, chlorinated C2 compounds, a kinetic simulation was performed and cross-checked with the experimental results to clarify the reactions mechanism.",

keywords = "CCl decomposition, Gliding arc, Plasma, Reaction mechanism",

author = "Antonius Indarto and Yang, {Dae Ryook} and Choi, {Jae Wook} and Hwaung Lee and Song, {Hyung Keun}",

note = "Funding Information: This study was supported by the National Research Laboratory Program of the Korea Ministry of Science and Technology. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.",

year = "2007",

month = aug,

doi = "10.1080/00986440701293363",

language = "English",

volume = "194",

pages = "1111--1125",

journal = "Chemical Engineering Communications",

issn = "0098-6445",

publisher = "Taylor and Francis Ltd.",

number = "8",

}

TY - JOUR

T1 - CCl4 decomposition by gliding arc plasma

T2 - Role of C2 compounds on products distribution

AU - Indarto, Antonius

AU - Yang, Dae Ryook

AU - Choi, Jae Wook

AU - Lee, Hwaung

AU - Song, Hyung Keun

N1 - Funding Information: This study was supported by the National Research Laboratory Program of the Korea Ministry of Science and Technology. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2007/8

Y1 - 2007/8

N2 - The goal of this work is to investigate the role of existing C2 compounds in the plasma reactions of carbon tetrachloride (CCl4) decomposition. The experiment of CCl4 decomposition was carried out by gliding arc plasma. The decomposition products were dominated by CO, CO2, and Cl2. The conversion of CCl4 into Cl2 and (CO + CO2) reaches ∼50% and ∼40%, respectively. Other chlorinated compounds were suspected to be produced, such as COCl, COCl2, and C2 compounds. In order to prove the existence of those compounds, for example, chlorinated C2 compounds, a kinetic simulation was performed and cross-checked with the experimental results to clarify the reactions mechanism.

AB - The goal of this work is to investigate the role of existing C2 compounds in the plasma reactions of carbon tetrachloride (CCl4) decomposition. The experiment of CCl4 decomposition was carried out by gliding arc plasma. The decomposition products were dominated by CO, CO2, and Cl2. The conversion of CCl4 into Cl2 and (CO + CO2) reaches ∼50% and ∼40%, respectively. Other chlorinated compounds were suspected to be produced, such as COCl, COCl2, and C2 compounds. In order to prove the existence of those compounds, for example, chlorinated C2 compounds, a kinetic simulation was performed and cross-checked with the experimental results to clarify the reactions mechanism.

KW - CCl decomposition

KW - Gliding arc

KW - Plasma

KW - Reaction mechanism

UR - http://www.scopus.com/inward/record.url?scp=34247891543&partnerID=8YFLogxK

U2 - 10.1080/00986440701293363

DO - 10.1080/00986440701293363

M3 - Article

AN - SCOPUS:34247891543

SN - 0098-6445

VL - 194

SP - 1111

EP - 1125

JO - Chemical Engineering Communications

JF - Chemical Engineering Communications

IS - 8

ER -