Changing the dielectric properties of BaTiO3 filled poly(phenylene oxide) composites by control of their structure

Yong Kyun Jang; Jong Chan Won; Ho Gyu Yoon

doi:10.1063/1.3194155

Changing the dielectric properties of BaTiO₃ filled poly(phenylene oxide) composites by control of their structure

Yong Kyun Jang, Jong Chan Won, Ho Gyu Yoon

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The dielectric properties of BaTiO₃ (BT) filled poly(phenylene oxide) (PPO) composites are investigated according to their structure, which is modified by filling the matrix with PPO-encapsulated BT particles and forming the semi-interpenetrating polymer network with triallyl isocyanurate (TAIC). Polymer encapsulation is most effective in lowering the permittivity and tan δ of the composite by suppressing the interface polarization. The copolymerization effect of TAIC is ignorable for a low dielectric matrix such as PPO. However, the dielectric values of the composites with low molecular weight-sized PPO, as the matrix, are decreased significantly by TAIC due to the constrained orientation polarization of the matrix.

Original language	English
Article number	052907
Journal	Applied Physics Letters
Volume	95
Issue number	5
DOIs	https://doi.org/10.1063/1.3194155
Publication status	Published - 2009

Bibliographical note

Funding Information:
This research was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy, Republic of Korea (Grant No. M 2008 01 0026).

ASJC Scopus subject areas

Physics and Astronomy (miscellaneous)

Access to Document

10.1063/1.3194155

Cite this

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title = "Changing the dielectric properties of BaTiO3 filled poly(phenylene oxide) composites by control of their structure",

abstract = "The dielectric properties of BaTiO3 (BT) filled poly(phenylene oxide) (PPO) composites are investigated according to their structure, which is modified by filling the matrix with PPO-encapsulated BT particles and forming the semi-interpenetrating polymer network with triallyl isocyanurate (TAIC). Polymer encapsulation is most effective in lowering the permittivity and tan δ of the composite by suppressing the interface polarization. The copolymerization effect of TAIC is ignorable for a low dielectric matrix such as PPO. However, the dielectric values of the composites with low molecular weight-sized PPO, as the matrix, are decreased significantly by TAIC due to the constrained orientation polarization of the matrix.",

author = "Jang, {Yong Kyun} and Won, {Jong Chan} and Yoon, {Ho Gyu}",

note = "Funding Information: This research was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy, Republic of Korea (Grant No. M 2008 01 0026).",

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AU - Jang, Yong Kyun

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AU - Yoon, Ho Gyu

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AB - The dielectric properties of BaTiO3 (BT) filled poly(phenylene oxide) (PPO) composites are investigated according to their structure, which is modified by filling the matrix with PPO-encapsulated BT particles and forming the semi-interpenetrating polymer network with triallyl isocyanurate (TAIC). Polymer encapsulation is most effective in lowering the permittivity and tan δ of the composite by suppressing the interface polarization. The copolymerization effect of TAIC is ignorable for a low dielectric matrix such as PPO. However, the dielectric values of the composites with low molecular weight-sized PPO, as the matrix, are decreased significantly by TAIC due to the constrained orientation polarization of the matrix.

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