Characteristics of reactive nitrogen compounds and other relevant trace gases in the atmosphere at urban and rural areas of Korea during May-June, 2004

Z. H. Shon; G. Lee; S. K. Song; M. Lee; J. Han; D. Lee

doi:10.1007/s10874-007-9088-4

Characteristics of reactive nitrogen compounds and other relevant trace gases in the atmosphere at urban and rural areas of Korea during May-June, 2004

Z. H. Shon, G. Lee, S. K. Song, M. Lee, J. Han, D. Lee

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

This study examines the general characteristics of reactive nitrogen oxides (NO_y) at urban and rural sites in terms of measurement- and modeling-based analyses. In this field study, NO_x at urban and rural sites were 92 and 89% of NO_y on average, respectively. HONO levels (e.g., 1.8 ppbv) at the urban site were significantly higher than those at the rural site by a factor of 4.5. HONO concentrations at the urban site during the night were clearly higher than those during the day, which were likely to result from heterogeneous reactions on the surfaces of airborne aerosols and/or grounds. In contrast, there were no significant differences of PAN concentrations in either the temporal or spatial distributions. The significantly low ratios of NO_z/NO_y at both sampling sites indicated a more limited chemical aging process in air mass. O₃ levels were weakly related to NO_x oxidation at both sites, especially at the rural site.

Original language	English
Pages (from-to)	203-218
Number of pages	16
Journal	Journal of Atmospheric Chemistry
Volume	58
Issue number	3
DOIs	https://doi.org/10.1007/s10874-007-9088-4
Publication status	Published - 2007 Nov

Bibliographical note

Funding Information:
Acknowledgments This research was financially supported by the Ministry of Environment and the Climate Environment System Research Center sponsored by the SRC program of Korea Science and Engineering Foundation.

Keywords

HONO
Modeling based analysis
Nitrogen oxides
Rural
Urban

ASJC Scopus subject areas

Environmental Chemistry
Atmospheric Science

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10.1007/s10874-007-9088-4

Cite this

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title = "Characteristics of reactive nitrogen compounds and other relevant trace gases in the atmosphere at urban and rural areas of Korea during May-June, 2004",

abstract = "This study examines the general characteristics of reactive nitrogen oxides (NOy) at urban and rural sites in terms of measurement- and modeling-based analyses. In this field study, NOx at urban and rural sites were 92 and 89% of NOy on average, respectively. HONO levels (e.g., 1.8 ppbv) at the urban site were significantly higher than those at the rural site by a factor of 4.5. HONO concentrations at the urban site during the night were clearly higher than those during the day, which were likely to result from heterogeneous reactions on the surfaces of airborne aerosols and/or grounds. In contrast, there were no significant differences of PAN concentrations in either the temporal or spatial distributions. The significantly low ratios of NOz/NOy at both sampling sites indicated a more limited chemical aging process in air mass. O3 levels were weakly related to NOx oxidation at both sites, especially at the rural site.",

keywords = "HONO, Modeling based analysis, Nitrogen oxides, Rural, Urban",

author = "Shon, {Z. H.} and G. Lee and Song, {S. K.} and M. Lee and J. Han and D. Lee",

note = "Funding Information: Acknowledgments This research was financially supported by the Ministry of Environment and the Climate Environment System Research Center sponsored by the SRC program of Korea Science and Engineering Foundation.",

year = "2007",

month = nov,

doi = "10.1007/s10874-007-9088-4",

language = "English",

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pages = "203--218",

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T1 - Characteristics of reactive nitrogen compounds and other relevant trace gases in the atmosphere at urban and rural areas of Korea during May-June, 2004

AU - Shon, Z. H.

AU - Lee, G.

AU - Song, S. K.

AU - Lee, M.

AU - Han, J.

AU - Lee, D.

N1 - Funding Information: Acknowledgments This research was financially supported by the Ministry of Environment and the Climate Environment System Research Center sponsored by the SRC program of Korea Science and Engineering Foundation.

PY - 2007/11

Y1 - 2007/11

N2 - This study examines the general characteristics of reactive nitrogen oxides (NOy) at urban and rural sites in terms of measurement- and modeling-based analyses. In this field study, NOx at urban and rural sites were 92 and 89% of NOy on average, respectively. HONO levels (e.g., 1.8 ppbv) at the urban site were significantly higher than those at the rural site by a factor of 4.5. HONO concentrations at the urban site during the night were clearly higher than those during the day, which were likely to result from heterogeneous reactions on the surfaces of airborne aerosols and/or grounds. In contrast, there were no significant differences of PAN concentrations in either the temporal or spatial distributions. The significantly low ratios of NOz/NOy at both sampling sites indicated a more limited chemical aging process in air mass. O3 levels were weakly related to NOx oxidation at both sites, especially at the rural site.

AB - This study examines the general characteristics of reactive nitrogen oxides (NOy) at urban and rural sites in terms of measurement- and modeling-based analyses. In this field study, NOx at urban and rural sites were 92 and 89% of NOy on average, respectively. HONO levels (e.g., 1.8 ppbv) at the urban site were significantly higher than those at the rural site by a factor of 4.5. HONO concentrations at the urban site during the night were clearly higher than those during the day, which were likely to result from heterogeneous reactions on the surfaces of airborne aerosols and/or grounds. In contrast, there were no significant differences of PAN concentrations in either the temporal or spatial distributions. The significantly low ratios of NOz/NOy at both sampling sites indicated a more limited chemical aging process in air mass. O3 levels were weakly related to NOx oxidation at both sites, especially at the rural site.

KW - HONO

KW - Modeling based analysis

KW - Nitrogen oxides

KW - Rural

KW - Urban

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DO - 10.1007/s10874-007-9088-4

M3 - Article

AN - SCOPUS:37549031371

SN - 0167-7764

VL - 58

SP - 203

EP - 218

JO - Journal of Atmospheric Chemistry

JF - Journal of Atmospheric Chemistry

IS - 3

ER -

Characteristics of reactive nitrogen compounds and other relevant trace gases in the atmosphere at urban and rural areas of Korea during May-June, 2004

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

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