Chemical characterization of outdoor and subway fine (PM_2.5–1.0) and coarse (PM_10–2.5) particulate matter in Seoul (Korea) by computer-controlled scanning electron microscopy (CCSEM)

Outdoor and indoor (subway) samples were collected by passive sampling in urban Seoul (Korea) and analyzed with computer-controlled scanning electron microscopy coupled with energy dispersive x-ray spectroscopy (CCSEM-EDX). Soil/road dust particles accounted for 42%–60% (by weight) of fine particulate matter larger than 1 µm (PM_2.5–1.0) in outdoor samples and 18% of PM_2.5–1.0 in subway samples. Iron-containing particles accounted for only 3%–6% in outdoor samples but 69% in subway samples. Qualitatively similar results were found for coarse particulate matter (PM_10–2.5) with soil/road dust particles dominating outdoor samples (66%–83%) and iron-containing particles contributing most to subway PM_10–2.5 (44%). As expected, soil/road dust particles comprised a greater mass fraction of PM_10–2.5 than PM_2.5–1.0. Also as expected, the mass fraction of iron-containing particles was substantially less in PM_10–2.5 than in PM_2.5–1.0. Results of this study are consistent with known emission sources in the area and with previous studies, which showed high concentrations of iron-containing particles in the subway compared to outdoor sites. Thus, passive sampling with CCSEM-EDX offers an inexpensive means to assess PM_2.5–1.0 and PM_10-2.5simultaneously and by composition at multiple locations.