Chemically resistant and thermally stable quantum dots prepared by shell encapsulation with cross-linkable block copolymer ligands

Jaewan Ko, Byeong Guk Jeong, Jun Hyuk Chang, Joonyoung F. Joung, Suk Young Yoon, Doh C. Lee, Sungnam Park, June Huh, Heesun Yang, Wan Ki Bae, Se Gyu Jang, Joona Bang

Research output: Contribution to journalArticlepeer-review

34 Citations (Scopus)


Endowing quantum dots (QDs) with robustness and durability have been one of the most important issues in this field, since the major limitations of QDs in practical applications are their thermal and oxidative instabilities. In this work, we propose a facile and effective passivation method to enhance the photochemical stability of QDs using polymeric double shell structures from thiol-terminated poly(methyl methacrylate-b-glycidyl methacrylate) (P(MMA-b-GMA)-SH) block copolymer ligands. To generate a densely cross-linked network, the cross-linking reaction of GMA epoxides in the PGMA block was conducted using a Lewis acid catalyst under an ambient environment to avoid affecting the photophysical properties of the pristine QDs. This provides QDs encapsulated with robust double layers consisting of highly transparent PMMA outer-shell and oxidation-protective cross-linked inner shell. Consequently, the resulting QDs exhibited exceptional tolerance to heat and oxidants when dispersed in organic solvents or QD-nanocomposite films, as demonstrated under various harsh conditions with respect to temperature and oxidant species. The present approach not only provides simple yet effective chemical means to enhance the thermochemical stability of QDs, but also offers a promising platform for the hybridization of QDs with polymeric materials for developing robust light-emitting or light-harvesting devices.

Original languageEnglish
Article number19
JournalNPG Asia Materials
Issue number1
Publication statusPublished - 2020 Dec 1

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIT) (No. 2018R1A2B2004508 and 2016M3A7B4910619) and by the Creative Materials Discovery Program through NRF grant funded by MSIT (2018M3D1A1058536).

Publisher Copyright:
© 2020, The Author(s).

ASJC Scopus subject areas

  • Modelling and Simulation
  • General Materials Science
  • Condensed Matter Physics


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