Chiral azide-bridged two-dimensional Cu(II) compounds showing a field-induced spin-flop transition

Young Sin You; Jung Hee Yoon; Hyoung Chan Kim; Chang Seop Hong

doi:10.1039/b507051a

Chiral azide-bridged two-dimensional Cu(II) compounds showing a field-induced spin-flop transition

Young Sin You, Jung Hee Yoon, Hyoung Chan Kim, Chang Seop Hong

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

64 Citations (Scopus)

Abstract

Two azide-bridged chiral Cu(II) compounds, [Cu(R,R-dacy)-(N ₃)₂]_n (1) (R,R-dacy = trans-(1R,2A)- diaminocyclohexane) and [Cu(S,S-dacy)(N₃)₂]_n, (2) (S,S-dacy = trans-(1S,2S)-diaminocyclohexane), with two-dimensional layer structures exhibiting end-to-end and end-on azide bridging patterns, were prepared and among them 1 was examined to show a field-induced spin-flop transition.

Original language	English
Pages (from-to)	4116-4118
Number of pages	3
Journal	Chemical Communications
Issue number	32
DOIs	https://doi.org/10.1039/b507051a
Publication status	Published - 2005 Aug 28

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Chiral azide-bridged two-dimensional Cu(II) compounds showing a field-induced spin-flop transition",

abstract = "Two azide-bridged chiral Cu(II) compounds, [Cu(R,R-dacy)-(N 3)2]n (1) (R,R-dacy = trans-(1R,2A)- diaminocyclohexane) and [Cu(S,S-dacy)(N3)2]n, (2) (S,S-dacy = trans-(1S,2S)-diaminocyclohexane), with two-dimensional layer structures exhibiting end-to-end and end-on azide bridging patterns, were prepared and among them 1 was examined to show a field-induced spin-flop transition.",

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T1 - Chiral azide-bridged two-dimensional Cu(II) compounds showing a field-induced spin-flop transition

AU - You, Young Sin

AU - Yoon, Jung Hee

AU - Kim, Hyoung Chan

AU - Hong, Chang Seop

PY - 2005/8/28

Y1 - 2005/8/28

N2 - Two azide-bridged chiral Cu(II) compounds, [Cu(R,R-dacy)-(N 3)2]n (1) (R,R-dacy = trans-(1R,2A)- diaminocyclohexane) and [Cu(S,S-dacy)(N3)2]n, (2) (S,S-dacy = trans-(1S,2S)-diaminocyclohexane), with two-dimensional layer structures exhibiting end-to-end and end-on azide bridging patterns, were prepared and among them 1 was examined to show a field-induced spin-flop transition.

AB - Two azide-bridged chiral Cu(II) compounds, [Cu(R,R-dacy)-(N 3)2]n (1) (R,R-dacy = trans-(1R,2A)- diaminocyclohexane) and [Cu(S,S-dacy)(N3)2]n, (2) (S,S-dacy = trans-(1S,2S)-diaminocyclohexane), with two-dimensional layer structures exhibiting end-to-end and end-on azide bridging patterns, were prepared and among them 1 was examined to show a field-induced spin-flop transition.

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Chiral azide-bridged two-dimensional Cu(II) compounds showing a field-induced spin-flop transition

Abstract

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