Chiral environment of catalytic sites in the chiral metal-organic frameworks

Misun Lee, Sung Min Shin, Nakcheol Jeong, Praveen K. Thallapally

    Research output: Contribution to journalArticlepeer-review

    18 Citations (Scopus)

    Abstract

    Chiral metal-organic frameworks are considered a useful platform in heterogeneous catalysis for enantioselective chemical transformations. However, it has been observed that the enantioselectivity is sensitive to the site at which the reaction takes place, even in a single crystal, since the chiral environment of the catalytic site varies according to its location, e.g., that of the surface is anisotropic, whereas that of the interior is isotropic.

    Original languageEnglish
    Pages (from-to)9349-9352
    Number of pages4
    JournalDalton Transactions
    Volume44
    Issue number20
    DOIs
    Publication statusPublished - 2015 May 28

    Bibliographical note

    Publisher Copyright:
    © The Royal Society of Chemistry 2015.

    ASJC Scopus subject areas

    • Inorganic Chemistry

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