Chiral environment of catalytic sites in the chiral metal-organic frameworks

Misun Lee; Sung Min Shin; Nakcheol Jeong; Praveen K. Thallapally

doi:10.1039/c5dt01322d

Chiral environment of catalytic sites in the chiral metal-organic frameworks

Misun Lee, Sung Min Shin, Nakcheol Jeong, Praveen K. Thallapally

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Chiral metal-organic frameworks are considered a useful platform in heterogeneous catalysis for enantioselective chemical transformations. However, it has been observed that the enantioselectivity is sensitive to the site at which the reaction takes place, even in a single crystal, since the chiral environment of the catalytic site varies according to its location, e.g., that of the surface is anisotropic, whereas that of the interior is isotropic.

Original language	English
Pages (from-to)	9349-9352
Number of pages	4
Journal	Dalton Transactions
Volume	44
Issue number	20
DOIs	https://doi.org/10.1039/c5dt01322d
Publication status	Published - 2015 May 28

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/c5dt01322d

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title = "Chiral environment of catalytic sites in the chiral metal-organic frameworks",

abstract = "Chiral metal-organic frameworks are considered a useful platform in heterogeneous catalysis for enantioselective chemical transformations. However, it has been observed that the enantioselectivity is sensitive to the site at which the reaction takes place, even in a single crystal, since the chiral environment of the catalytic site varies according to its location, e.g., that of the surface is anisotropic, whereas that of the interior is isotropic.",

author = "Misun Lee and Shin, {Sung Min} and Nakcheol Jeong and Thallapally, {Praveen K.}",

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AU - Shin, Sung Min

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AU - Thallapally, Praveen K.

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N2 - Chiral metal-organic frameworks are considered a useful platform in heterogeneous catalysis for enantioselective chemical transformations. However, it has been observed that the enantioselectivity is sensitive to the site at which the reaction takes place, even in a single crystal, since the chiral environment of the catalytic site varies according to its location, e.g., that of the surface is anisotropic, whereas that of the interior is isotropic.

AB - Chiral metal-organic frameworks are considered a useful platform in heterogeneous catalysis for enantioselective chemical transformations. However, it has been observed that the enantioselectivity is sensitive to the site at which the reaction takes place, even in a single crystal, since the chiral environment of the catalytic site varies according to its location, e.g., that of the surface is anisotropic, whereas that of the interior is isotropic.

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Chiral environment of catalytic sites in the chiral metal-organic frameworks

Abstract

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