'Cleft-form' electrochemical anion chemosensor with amide and triazole donor groups

Qian Yong Cao, Tuhin Pradhan, Min Hee Lee, Dong Hoon Choi, Jong Seung Kim

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)

Abstract

A novel 'cleft-form' electrochemical anion receptor bearing amide and triazole donor groups, 1, has been synthesized and characterized. Among various anions, 1 shows a significant anodic shift response for H 2PO4- and F -, with its multiple N-H⋯anion and C-H⋯anion interactions, which is supported by theoretical calculation and NMR titration results.

Original languageEnglish
Pages (from-to)4917-4920
Number of pages4
JournalTetrahedron Letters
Volume53
Issue number37
DOIs
Publication statusPublished - 2012 Sept 12

Bibliographical note

Funding Information:
This work was supported by the CRI project (20120000243) (J.S.K.). Q.-Y.C. acknowledges the funds from the National Nature Science Foundation of China (No. 21162017). DHC and TP also acknowledge Priority Research Centers Program through the NRF funded by the Ministry of Education, Science and Technology (NRF20120005860).

Keywords

  • 'Cleft-form' receptor
  • Anions sensing
  • Ferrocene

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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