TY - JOUR
T1 - Coconut-Water-Mediated Carbonaceous Electrode
T2 - A Promising Eco-Friendly Material for Bifunctional Water Splitting Application
AU - Raut, Siddheshwar D.
AU - Shinde, Nanasaheb M.
AU - Nakate, Yogesh T.
AU - Ghule, Balaji G.
AU - Gore, Shyam K.
AU - Shaikh, Shoyebmohamad F.
AU - Pak, James J.
AU - Al-Enizi, Abdullah M.
AU - Mane, Rajaram S.
N1 - Publisher Copyright:
©
PY - 2021/5/18
Y1 - 2021/5/18
N2 - The organic and eco-friendly materials are extended to prevail over the worldwide energy crisis where bio-inspired carbonaceous electrode materials are being prepared from biogenic items and wastes. Here, coconut water is sprayed over three-dimensional (3D) nickel foam for obtaining a carbonaceous electrode material, i.e., C@Ni-F. The as-prepared C@Ni-F electrode has been used for structural elucidation and morphology evolution studies. Field emission scanning electron microscopy analysis confirms the vertically grown nanosheets of the C@Ni-F electrode, which is further employed in the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), where excellent OER and HER performances with small overpotentials of 219 and 122 mV and with stumpy Tafel slopes, i.e., 27 and 53 mV dec-1, are respectively obtained, suggesting a bifunctional potential of the sprayed electrode material. Moreover, sustainable bifunctional performance of C@Ni-F proves considerable chemical stability and moderate mechanical robustness against long-term operation, suggesting that, in addition to being a healthy drink to mankind, coconut water can also be used for water splitting applications.
AB - The organic and eco-friendly materials are extended to prevail over the worldwide energy crisis where bio-inspired carbonaceous electrode materials are being prepared from biogenic items and wastes. Here, coconut water is sprayed over three-dimensional (3D) nickel foam for obtaining a carbonaceous electrode material, i.e., C@Ni-F. The as-prepared C@Ni-F electrode has been used for structural elucidation and morphology evolution studies. Field emission scanning electron microscopy analysis confirms the vertically grown nanosheets of the C@Ni-F electrode, which is further employed in the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), where excellent OER and HER performances with small overpotentials of 219 and 122 mV and with stumpy Tafel slopes, i.e., 27 and 53 mV dec-1, are respectively obtained, suggesting a bifunctional potential of the sprayed electrode material. Moreover, sustainable bifunctional performance of C@Ni-F proves considerable chemical stability and moderate mechanical robustness against long-term operation, suggesting that, in addition to being a healthy drink to mankind, coconut water can also be used for water splitting applications.
UR - http://www.scopus.com/inward/record.url?scp=85106509029&partnerID=8YFLogxK
U2 - 10.1021/acsomega.1c00641
DO - 10.1021/acsomega.1c00641
M3 - Article
AN - SCOPUS:85106509029
SN - 2470-1343
VL - 6
SP - 12623
EP - 12630
JO - ACS Omega
JF - ACS Omega
IS - 19
ER -