Coexistence of spin canting and metamagnetism in a one-dimensional Mn(III) complex bridged by a single end-to-end azide

Hee Ko Hyun; Hak Lim Jeong; Chan Kim Hyoung; Seop Hong Chang

doi:10.1021/ic061415+

Coexistence of spin canting and metamagnetism in a one-dimensional Mn(III) complex bridged by a single end-to-end azide

Hee Ko Hyun
, Hak Lim Jeong
, Chan Kim Hyoung
, Seop Hong Chang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Two manganese(III) azide complexes capped with tetradentate Schiff bases were characterized structurally and magnetically. The replacement of halogens on the Schiff bases leads to a drastic structural alteration from a dimer (1) bridged by phenoxide to a one-dimensional chain (2) linked by azide in a single end-to-end mode. Notably, magnetic studies of 2 show the concomitant existence of spin canting and metamagnetism.

Original language	English
Pages (from-to)	8847-8849
Number of pages	3
Journal	Inorganic Chemistry
Volume	45
Issue number	22
DOIs	https://doi.org/10.1021/ic061415+
Publication status	Published - 2006 Oct 30

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic061415+

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abstract = "Two manganese(III) azide complexes capped with tetradentate Schiff bases were characterized structurally and magnetically. The replacement of halogens on the Schiff bases leads to a drastic structural alteration from a dimer (1) bridged by phenoxide to a one-dimensional chain (2) linked by azide in a single end-to-end mode. Notably, magnetic studies of 2 show the concomitant existence of spin canting and metamagnetism.",

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AU - Jeong, Hak Lim

AU - Hyoung, Chan Kim

AU - Chang, Seop Hong

PY - 2006/10/30

Y1 - 2006/10/30

N2 - Two manganese(III) azide complexes capped with tetradentate Schiff bases were characterized structurally and magnetically. The replacement of halogens on the Schiff bases leads to a drastic structural alteration from a dimer (1) bridged by phenoxide to a one-dimensional chain (2) linked by azide in a single end-to-end mode. Notably, magnetic studies of 2 show the concomitant existence of spin canting and metamagnetism.

AB - Two manganese(III) azide complexes capped with tetradentate Schiff bases were characterized structurally and magnetically. The replacement of halogens on the Schiff bases leads to a drastic structural alteration from a dimer (1) bridged by phenoxide to a one-dimensional chain (2) linked by azide in a single end-to-end mode. Notably, magnetic studies of 2 show the concomitant existence of spin canting and metamagnetism.

UR - https://www.scopus.com/pages/publications/33751392872

U2 - 10.1021/ic061415+

DO - 10.1021/ic061415+

M3 - Article

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AN - SCOPUS:33751392872

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JF - Inorganic Chemistry

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ER -

Coexistence of spin canting and metamagnetism in a one-dimensional Mn(III) complex bridged by a single end-to-end azide

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ASJC Scopus subject areas

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