Comparative study on ternary spinel cathode Zn–Mn–O microspheres for aqueous rechargeable zinc-ion batteries

Jae Wan Lee; Seung Deok Seo; Dong Wan Kim

doi:10.1016/j.jallcom.2019.06.051

Comparative study on ternary spinel cathode Zn–Mn–O microspheres for aqueous rechargeable zinc-ion batteries

Jae Wan Lee, Seung Deok Seo, Dong Wan Kim

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

We demonstrate the cation ratio-controlled synthesis of ZnMn₂O₄ and Zn_1.67Mn_1.33O₄ aggregated microspheres. The carbonate precursor was synthesized by a solvothermal reaction, and then completely converted to oxide by calcination at 600 °C with a controlled cationic ratio. The prepared ternary oxide has a nanoparticle-aggregated morphology and uniform size distribution. The electrochemical properties were investigated by cyclic voltammetry and constant current charge-discharge measurements. The Zn_1.67Mn_1.33O₄ electrode reveals better performance for Zn²⁺ storage than the other, delivering 175 mA h g⁻¹ after 40 cycles. After the electrochemical test, ex situ analysis was conducted to identify the Zn²⁺ storage mechanisms. From these results, we confirm that the Zn_1.67Mn_1.33O₄ cathode is a promising Zn²⁺ storage material for environmental friendly aqueous rechargeable Zn-ion batteries.

Original language	English
Pages (from-to)	478-482
Number of pages	5
Journal	Journal of Alloys and Compounds
Volume	800
DOIs	https://doi.org/10.1016/j.jallcom.2019.06.051
Publication status	Published - 2019 Sept 5

Bibliographical note

Funding Information:
This work is supported by the National Research Foundation of Korea Grant funded by the Ministry of Science and ICT, South Korea (2019R1A2B5B02070203).

Funding Information:
This work is supported by the National Research Foundation of Korea Grant funded by the Ministry of Science and ICT, South Korea ( 2019R1A2B5B02070203 ).

Publisher Copyright:
© 2019 Elsevier B.V.

Keywords

Aqueous Zn-ion batteries
Cathode materials
Microspheres
Spinel structures
Zinc manganese oxides

ASJC Scopus subject areas

Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/j.jallcom.2019.06.051

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title = "Comparative study on ternary spinel cathode Zn–Mn–O microspheres for aqueous rechargeable zinc-ion batteries",

abstract = "We demonstrate the cation ratio-controlled synthesis of ZnMn2O4 and Zn1.67Mn1.33O4 aggregated microspheres. The carbonate precursor was synthesized by a solvothermal reaction, and then completely converted to oxide by calcination at 600 °C with a controlled cationic ratio. The prepared ternary oxide has a nanoparticle-aggregated morphology and uniform size distribution. The electrochemical properties were investigated by cyclic voltammetry and constant current charge-discharge measurements. The Zn1.67Mn1.33O4 electrode reveals better performance for Zn2+ storage than the other, delivering 175 mA h g−1 after 40 cycles. After the electrochemical test, ex situ analysis was conducted to identify the Zn2+ storage mechanisms. From these results, we confirm that the Zn1.67Mn1.33O4 cathode is a promising Zn2+ storage material for environmental friendly aqueous rechargeable Zn-ion batteries.",

keywords = "Aqueous Zn-ion batteries, Cathode materials, Microspheres, Spinel structures, Zinc manganese oxides",

author = "Lee, {Jae Wan} and Seo, {Seung Deok} and Kim, {Dong Wan}",

note = "Funding Information: This work is supported by the National Research Foundation of Korea Grant funded by the Ministry of Science and ICT, South Korea (2019R1A2B5B02070203). Funding Information: This work is supported by the National Research Foundation of Korea Grant funded by the Ministry of Science and ICT, South Korea ( 2019R1A2B5B02070203 ). Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",

year = "2019",

month = sep,

day = "5",

doi = "10.1016/j.jallcom.2019.06.051",

language = "English",

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AU - Lee, Jae Wan

AU - Seo, Seung Deok

AU - Kim, Dong Wan

N1 - Funding Information: This work is supported by the National Research Foundation of Korea Grant funded by the Ministry of Science and ICT, South Korea (2019R1A2B5B02070203). Funding Information: This work is supported by the National Research Foundation of Korea Grant funded by the Ministry of Science and ICT, South Korea ( 2019R1A2B5B02070203 ). Publisher Copyright: © 2019 Elsevier B.V.

PY - 2019/9/5

Y1 - 2019/9/5

N2 - We demonstrate the cation ratio-controlled synthesis of ZnMn2O4 and Zn1.67Mn1.33O4 aggregated microspheres. The carbonate precursor was synthesized by a solvothermal reaction, and then completely converted to oxide by calcination at 600 °C with a controlled cationic ratio. The prepared ternary oxide has a nanoparticle-aggregated morphology and uniform size distribution. The electrochemical properties were investigated by cyclic voltammetry and constant current charge-discharge measurements. The Zn1.67Mn1.33O4 electrode reveals better performance for Zn2+ storage than the other, delivering 175 mA h g−1 after 40 cycles. After the electrochemical test, ex situ analysis was conducted to identify the Zn2+ storage mechanisms. From these results, we confirm that the Zn1.67Mn1.33O4 cathode is a promising Zn2+ storage material for environmental friendly aqueous rechargeable Zn-ion batteries.

AB - We demonstrate the cation ratio-controlled synthesis of ZnMn2O4 and Zn1.67Mn1.33O4 aggregated microspheres. The carbonate precursor was synthesized by a solvothermal reaction, and then completely converted to oxide by calcination at 600 °C with a controlled cationic ratio. The prepared ternary oxide has a nanoparticle-aggregated morphology and uniform size distribution. The electrochemical properties were investigated by cyclic voltammetry and constant current charge-discharge measurements. The Zn1.67Mn1.33O4 electrode reveals better performance for Zn2+ storage than the other, delivering 175 mA h g−1 after 40 cycles. After the electrochemical test, ex situ analysis was conducted to identify the Zn2+ storage mechanisms. From these results, we confirm that the Zn1.67Mn1.33O4 cathode is a promising Zn2+ storage material for environmental friendly aqueous rechargeable Zn-ion batteries.

KW - Aqueous Zn-ion batteries

KW - Cathode materials

KW - Microspheres

KW - Spinel structures

KW - Zinc manganese oxides

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DO - 10.1016/j.jallcom.2019.06.051

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SN - 0925-8388

VL - 800

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JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

ER -

Comparative study on ternary spinel cathode Zn–Mn–O microspheres for aqueous rechargeable zinc-ion batteries

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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