Comparison of effects of multiple oxidants with an ultrasonic system under unified system conditions for bisphenol A degradation

Shiyu Sun; Yangmin Ren; Fengshi Guo; Yongyue Zhou; Mingcan Cui; Junjun Ma; Zhengchang Han; Jeehyeong Khim

doi:10.1016/j.chemosphere.2023.138526

Comparison of effects of multiple oxidants with an ultrasonic system under unified system conditions for bisphenol A degradation

Shiyu Sun, Yangmin Ren, Fengshi Guo, Yongyue Zhou, Mingcan Cui, Junjun Ma, Zhengchang Han, Jeehyeong Khim

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Bisphenol A (BPA) as a trace contaminant has been reported, due to widespread use in the plastics industry. This study applied the 35 kHz ultrasound (US) to activate four different common oxidants (H₂O₂, HSO₅⁻, S₂O₈²⁻, and IO₄⁻) for BPA degradation. With increasing initial concentration of oxidants, the degradation rate of BPA increased. The synergy index confirmed that a synergistic relationship between US and oxidants. This study also examined the impact of pH and temperature. The results showed that the kinetic constants of US, US-H₂O₂, US-HSO₅^- and US-IO₄⁻decreased when the pH increased from 6 to 11. The optimal pH for US-S₂O₈²⁻ was 8. Notably, increasing temperature decreased the performance of US, US-H₂O₂, and US-IO₄^- systems, while it could increase the degradation of BPA in US-S₂O₈²⁻ and US-HSO₅^-. The activation energy for BPA decomposition using the US-IO₄^- system was the lowest, at 0.453nullkJnullmol⁻¹, and the synergy index was the highest at 2.22. Additionally, the ΔG# value was found to be 2.11 + 0.29T when the temperature ranged from 25 °C to 45 °C. The main oxidation contribution is achieved by hydroxyl radicals in scavenger test. The mechanism of activation of US-oxidant is heat and electron transfer. In the case of the US-IO₄^- system, the economic analysis yielded 271 kwh m⁻³, which was approximately 2.4 times lower than that of the US process.

Original language	English
Article number	138526
Journal	Chemosphere
Volume	329
DOIs	https://doi.org/10.1016/j.chemosphere.2023.138526
Publication status	Published - 2023 Jul

Bibliographical note

Funding Information:
Funding: This work was supported by the Korean Ministry of the Environment as a Subsurface Environment Management ( SEM ) project (No. 2021002170003 ) and the Jiangsu Provincial Department of Science project (No. BZ2021026 ) and Jiangsu Provincial Nanjing City, Department of Science project ( No.202201002 ). We thank Dr. Yun Gyong Ahn (Korea Basic Science Institute, Western Seoul Center) for helpful discussions about the data analysis.

Funding Information:
Funding: This work was supported by the Korean Ministry of the Environment as a Subsurface Environment Management (SEM) project (No.2021002170003) and the Jiangsu Provincial Department of Science project (No. BZ2021026) and Jiangsu Provincial Nanjing City, Department of Science project (No.202201002). We thank Dr. Yun Gyong Ahn (Korea Basic Science Institute, Western Seoul Center) for helpful discussions about the data analysis.

Publisher Copyright:
© 2023 Elsevier Ltd

Keywords

Activation energy
Bisphenol A
Kinetics
Mechanism
Oxidant
Ultrasonic activation

ASJC Scopus subject areas

Environmental Engineering
Environmental Chemistry
General Chemistry
Pollution
Public Health, Environmental and Occupational Health
Health, Toxicology and Mutagenesis

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.chemosphere.2023.138526

Cite this

@article{959707646ab54688bf34133ba846269a,

title = "Comparison of effects of multiple oxidants with an ultrasonic system under unified system conditions for bisphenol A degradation",

abstract = "Bisphenol A (BPA) as a trace contaminant has been reported, due to widespread use in the plastics industry. This study applied the 35 kHz ultrasound (US) to activate four different common oxidants (H2O2, HSO5−, S2O82−, and IO4−) for BPA degradation. With increasing initial concentration of oxidants, the degradation rate of BPA increased. The synergy index confirmed that a synergistic relationship between US and oxidants. This study also examined the impact of pH and temperature. The results showed that the kinetic constants of US, US-H2O2, US-HSO5- and US-IO4−decreased when the pH increased from 6 to 11. The optimal pH for US-S2O82− was 8. Notably, increasing temperature decreased the performance of US, US-H2O2, and US-IO4- systems, while it could increase the degradation of BPA in US-S2O82− and US-HSO5-. The activation energy for BPA decomposition using the US-IO4- system was the lowest, at 0.453nullkJnullmol−1, and the synergy index was the highest at 2.22. Additionally, the ΔG# value was found to be 2.11 + 0.29T when the temperature ranged from 25 °C to 45 °C. The main oxidation contribution is achieved by hydroxyl radicals in scavenger test. The mechanism of activation of US-oxidant is heat and electron transfer. In the case of the US-IO4- system, the economic analysis yielded 271 kwh m−3, which was approximately 2.4 times lower than that of the US process.",

keywords = "Activation energy, Bisphenol A, Kinetics, Mechanism, Oxidant, Ultrasonic activation",

author = "Shiyu Sun and Yangmin Ren and Fengshi Guo and Yongyue Zhou and Mingcan Cui and Junjun Ma and Zhengchang Han and Jeehyeong Khim",

note = "Funding Information: Funding: This work was supported by the Korean Ministry of the Environment as a Subsurface Environment Management ( SEM ) project (No. 2021002170003 ) and the Jiangsu Provincial Department of Science project (No. BZ2021026 ) and Jiangsu Provincial Nanjing City, Department of Science project ( No.202201002 ). We thank Dr. Yun Gyong Ahn (Korea Basic Science Institute, Western Seoul Center) for helpful discussions about the data analysis. Funding Information: Funding: This work was supported by the Korean Ministry of the Environment as a Subsurface Environment Management (SEM) project (No.2021002170003) and the Jiangsu Provincial Department of Science project (No. BZ2021026) and Jiangsu Provincial Nanjing City, Department of Science project (No.202201002). We thank Dr. Yun Gyong Ahn (Korea Basic Science Institute, Western Seoul Center) for helpful discussions about the data analysis. Publisher Copyright: {\textcopyright} 2023 Elsevier Ltd",

year = "2023",

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doi = "10.1016/j.chemosphere.2023.138526",

language = "English",

volume = "329",

journal = "Chemosphere",

issn = "0045-6535",

publisher = "Elsevier Ltd",

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T1 - Comparison of effects of multiple oxidants with an ultrasonic system under unified system conditions for bisphenol A degradation

AU - Sun, Shiyu

AU - Ren, Yangmin

AU - Guo, Fengshi

AU - Zhou, Yongyue

AU - Cui, Mingcan

AU - Ma, Junjun

AU - Han, Zhengchang

AU - Khim, Jeehyeong

N1 - Funding Information: Funding: This work was supported by the Korean Ministry of the Environment as a Subsurface Environment Management ( SEM ) project (No. 2021002170003 ) and the Jiangsu Provincial Department of Science project (No. BZ2021026 ) and Jiangsu Provincial Nanjing City, Department of Science project ( No.202201002 ). We thank Dr. Yun Gyong Ahn (Korea Basic Science Institute, Western Seoul Center) for helpful discussions about the data analysis. Funding Information: Funding: This work was supported by the Korean Ministry of the Environment as a Subsurface Environment Management (SEM) project (No.2021002170003) and the Jiangsu Provincial Department of Science project (No. BZ2021026) and Jiangsu Provincial Nanjing City, Department of Science project (No.202201002). We thank Dr. Yun Gyong Ahn (Korea Basic Science Institute, Western Seoul Center) for helpful discussions about the data analysis. Publisher Copyright: © 2023 Elsevier Ltd

PY - 2023/7

Y1 - 2023/7

N2 - Bisphenol A (BPA) as a trace contaminant has been reported, due to widespread use in the plastics industry. This study applied the 35 kHz ultrasound (US) to activate four different common oxidants (H2O2, HSO5−, S2O82−, and IO4−) for BPA degradation. With increasing initial concentration of oxidants, the degradation rate of BPA increased. The synergy index confirmed that a synergistic relationship between US and oxidants. This study also examined the impact of pH and temperature. The results showed that the kinetic constants of US, US-H2O2, US-HSO5- and US-IO4−decreased when the pH increased from 6 to 11. The optimal pH for US-S2O82− was 8. Notably, increasing temperature decreased the performance of US, US-H2O2, and US-IO4- systems, while it could increase the degradation of BPA in US-S2O82− and US-HSO5-. The activation energy for BPA decomposition using the US-IO4- system was the lowest, at 0.453nullkJnullmol−1, and the synergy index was the highest at 2.22. Additionally, the ΔG# value was found to be 2.11 + 0.29T when the temperature ranged from 25 °C to 45 °C. The main oxidation contribution is achieved by hydroxyl radicals in scavenger test. The mechanism of activation of US-oxidant is heat and electron transfer. In the case of the US-IO4- system, the economic analysis yielded 271 kwh m−3, which was approximately 2.4 times lower than that of the US process.

AB - Bisphenol A (BPA) as a trace contaminant has been reported, due to widespread use in the plastics industry. This study applied the 35 kHz ultrasound (US) to activate four different common oxidants (H2O2, HSO5−, S2O82−, and IO4−) for BPA degradation. With increasing initial concentration of oxidants, the degradation rate of BPA increased. The synergy index confirmed that a synergistic relationship between US and oxidants. This study also examined the impact of pH and temperature. The results showed that the kinetic constants of US, US-H2O2, US-HSO5- and US-IO4−decreased when the pH increased from 6 to 11. The optimal pH for US-S2O82− was 8. Notably, increasing temperature decreased the performance of US, US-H2O2, and US-IO4- systems, while it could increase the degradation of BPA in US-S2O82− and US-HSO5-. The activation energy for BPA decomposition using the US-IO4- system was the lowest, at 0.453nullkJnullmol−1, and the synergy index was the highest at 2.22. Additionally, the ΔG# value was found to be 2.11 + 0.29T when the temperature ranged from 25 °C to 45 °C. The main oxidation contribution is achieved by hydroxyl radicals in scavenger test. The mechanism of activation of US-oxidant is heat and electron transfer. In the case of the US-IO4- system, the economic analysis yielded 271 kwh m−3, which was approximately 2.4 times lower than that of the US process.

KW - Activation energy

KW - Bisphenol A

KW - Kinetics

KW - Mechanism

KW - Oxidant

KW - Ultrasonic activation

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DO - 10.1016/j.chemosphere.2023.138526

M3 - Article

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SN - 0045-6535

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Comparison of effects of multiple oxidants with an ultrasonic system under unified system conditions for bisphenol A degradation

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

UN SDGs

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