Conformal perovskite films on 100 cm2 textured silicon surface using two-step vacuum process

Jae Keun Hwang, Sang Won Lee, Wonkyu Lee, Soohyun Bae, Kyungjin Cho, Seongtak Kim, Solhee Lee, Ji Yeon Hyun, Yoonmook Kang, Hae Seok Lee, Donghwan Kim

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

In this study, perovskite thin films (PFs) were conformally deposited on 100 cm2 textured silicon substrates using a two-step vacuum process. The PFs were fabricated by converting thin films of a sputtered-PbO precursor using the chemical vapor deposition process. The conversion of PbO thin films into PFs was confirmed by X-ray diffractometry. The uniformity of reflectance and thickness was higher than 86% and 92%, respectively, on 100 cm2 textured substrate. We applied methylammonium vapor treatment for complete conversion without residual layer and the power conversion efficiency was 10.2% on a glass/FTO/TiO2/MAPbI3/Spiro-MeOTAD/Au structure.

Original languageEnglish
Article number137694
JournalThin Solid Films
Volume693
DOIs
Publication statusPublished - 2020 Jan 1

Bibliographical note

Funding Information:
This work was supported by the Korea Institute of Energy Technology Evaluation and Planning (grant number 20173030014370 ); the Technology Development Program to Solve Climate Changes of the National Research Foundation (NRF) funded by the Ministry of Science and ICT (grant number 2017M1A2A2087351 ); the “Human Resources Program in Energy Technology” of the Korea Institute of Energy Technology Evaluation and Planning, with financial support from the Ministry of Trade, Industry and Energy , Republic of Korea (grant number 20154030200760 ). This work was also conducted under the framework of the Research and Development Program of the Korea Institute of Energy Research (KIER) (B9-2411).

Funding Information:
This work was supported by the Korea Institute of Energy Technology Evaluation and Planning (grant number 20173030014370); the Technology Development Program to Solve Climate Changes of the National Research Foundation (NRF) funded by the Ministry of Science and ICT (grant number 2017M1A2A2087351); the “Human Resources Program in Energy Technology” of the Korea Institute of Energy Technology Evaluation and Planning, with financial support from the Ministry of Trade, Industry and Energy, Republic of Korea (grant number 20154030200760). This work was also conducted under the framework of the Research and Development Program of the Korea Institute of Energy Research (KIER) (B9-2411).

Publisher Copyright:
© 2019 Elsevier B.V.

Keywords

  • Chemical vapor deposition
  • Large area
  • Perovskite solar cells
  • Sputtering
  • Textured silicon

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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