Construction of composite particles with monolayered poly(styrene-co-acrylic acid) spheres on gold surface via heterocoagulation

Jong Hyuk Park; Sangwook Woo; Jung Hyun Kim; Raehyun Kim; Junkyung Kim; Sang Soo Lee

doi:10.1016/j.matlet.2008.05.039

Construction of composite particles with monolayered poly(styrene-co-acrylic acid) spheres on gold surface via heterocoagulation

Jong Hyuk Park, Sangwook Woo, Jung Hyun Kim, Raehyun Kim, Junkyung Kim, Sang Soo Lee

KU-KIST Graduate School of Converging Science and Technology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Composite particles are successfully fabricated in a shape of bead-on-bead through a heterocoagulation. Submicron poly(styrene-co-acrylic acid) (PSAA) spheres are prepared and used as guest materials of composite particles. The spheres adsorb on the gold surface of a host material in perfect monolayered form and the pH dependence of the adsorption degree is also investigated. At strong acidic condition, the spheres are effectively adsorbed on the host materials, while the adsorption efficiency dramatically decreases with increasing pH due to the deprotonation of carboxyl groups at the surface of the spheres. Even though the composite particles are immersed in good solvents of PSAA for 12 h, the particles exhibit excellent adsorption stability.

Original language	English
Pages (from-to)	3916-3918
Number of pages	3
Journal	Materials Letters
Volume	62
Issue number	23
DOIs	https://doi.org/10.1016/j.matlet.2008.05.039
Publication status	Published - 2008 Aug 31

Keywords

Composite materials
Gold
Heterocoagulation
Microstructure
Monolayered adsorption

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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10.1016/j.matlet.2008.05.039

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title = "Construction of composite particles with monolayered poly(styrene-co-acrylic acid) spheres on gold surface via heterocoagulation",

abstract = "Composite particles are successfully fabricated in a shape of bead-on-bead through a heterocoagulation. Submicron poly(styrene-co-acrylic acid) (PSAA) spheres are prepared and used as guest materials of composite particles. The spheres adsorb on the gold surface of a host material in perfect monolayered form and the pH dependence of the adsorption degree is also investigated. At strong acidic condition, the spheres are effectively adsorbed on the host materials, while the adsorption efficiency dramatically decreases with increasing pH due to the deprotonation of carboxyl groups at the surface of the spheres. Even though the composite particles are immersed in good solvents of PSAA for 12 h, the particles exhibit excellent adsorption stability.",

keywords = "Composite materials, Gold, Heterocoagulation, Microstructure, Monolayered adsorption",

author = "Park, {Jong Hyuk} and Sangwook Woo and Kim, {Jung Hyun} and Raehyun Kim and Junkyung Kim and Lee, {Sang Soo}",

note = "Funding Information: This work was supported by the Ministry of Commerce, Industry and Energy (MOCIE) through the project of NGNT (No. 10024135-2005-11), and the Fundamental R&D Program (KIST grant number: 2M19690) for Core Technology of Materials, Korea.",

year = "2008",

month = aug,

day = "31",

doi = "10.1016/j.matlet.2008.05.039",

language = "English",

volume = "62",

pages = "3916--3918",

journal = "Materials Letters",

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T1 - Construction of composite particles with monolayered poly(styrene-co-acrylic acid) spheres on gold surface via heterocoagulation

AU - Park, Jong Hyuk

AU - Woo, Sangwook

AU - Kim, Jung Hyun

AU - Kim, Raehyun

AU - Kim, Junkyung

AU - Lee, Sang Soo

N1 - Funding Information: This work was supported by the Ministry of Commerce, Industry and Energy (MOCIE) through the project of NGNT (No. 10024135-2005-11), and the Fundamental R&D Program (KIST grant number: 2M19690) for Core Technology of Materials, Korea.

PY - 2008/8/31

Y1 - 2008/8/31

N2 - Composite particles are successfully fabricated in a shape of bead-on-bead through a heterocoagulation. Submicron poly(styrene-co-acrylic acid) (PSAA) spheres are prepared and used as guest materials of composite particles. The spheres adsorb on the gold surface of a host material in perfect monolayered form and the pH dependence of the adsorption degree is also investigated. At strong acidic condition, the spheres are effectively adsorbed on the host materials, while the adsorption efficiency dramatically decreases with increasing pH due to the deprotonation of carboxyl groups at the surface of the spheres. Even though the composite particles are immersed in good solvents of PSAA for 12 h, the particles exhibit excellent adsorption stability.

AB - Composite particles are successfully fabricated in a shape of bead-on-bead through a heterocoagulation. Submicron poly(styrene-co-acrylic acid) (PSAA) spheres are prepared and used as guest materials of composite particles. The spheres adsorb on the gold surface of a host material in perfect monolayered form and the pH dependence of the adsorption degree is also investigated. At strong acidic condition, the spheres are effectively adsorbed on the host materials, while the adsorption efficiency dramatically decreases with increasing pH due to the deprotonation of carboxyl groups at the surface of the spheres. Even though the composite particles are immersed in good solvents of PSAA for 12 h, the particles exhibit excellent adsorption stability.

KW - Composite materials

KW - Gold

KW - Heterocoagulation

KW - Microstructure

KW - Monolayered adsorption

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DO - 10.1016/j.matlet.2008.05.039

M3 - Article

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SN - 0167-577X

VL - 62

SP - 3916

EP - 3918

JO - Materials Letters

JF - Materials Letters

IS - 23

ER -

Construction of composite particles with monolayered poly(styrene-co-acrylic acid) spheres on gold surface via heterocoagulation

Abstract

Keywords

ASJC Scopus subject areas

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