Control of Interchain Antiferromagnetic Coupling in Porous Co(II)-Based Metal-Organic Frameworks by Tuning the Aromatic Linker Length: How Far Does Magnetic Interaction Propagate?

Kwang Soo Lim; Woo Ram Lee; Han Geul Lee; Dong Won Kang; Jeong Hwa Song; Jeremy Hilgar; Jeffrey D. Rinehart; Dohyun Moon; Chang Seop Hong

doi:10.1021/acs.inorgchem.7b00899

Control of Interchain Antiferromagnetic Coupling in Porous Co(II)-Based Metal-Organic Frameworks by Tuning the Aromatic Linker Length: How Far Does Magnetic Interaction Propagate?

Kwang Soo Lim, Woo Ram Lee, Han Geul Lee, Dong Won Kang, Jeong Hwa Song, Jeremy Hilgar, Jeffrey D. Rinehart, Dohyun Moon, Chang Seop Hong

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Three MOF-74-type Co(II) frameworks with one-dimensional hexagonal channels have been prepared. Co(II) spins in a chain are ferromagnetically coupled through carboxylate and phenoxide bridges. Interchain antiferromagnetic couplings via aromatic ring pathways operate over a Co-Co length shorter than ?10.9 Å, resulting in a field-induced metamagnetic transition, while being absent over lengths longer than ?14.7 Å.

Original language	English
Pages (from-to)	7443-7448
Number of pages	6
Journal	Inorganic Chemistry
Volume	56
Issue number	13
DOIs	https://doi.org/10.1021/acs.inorgchem.7b00899
Publication status	Published - 2017 Jul 3

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/acs.inorgchem.7b00899

Cite this

Lim, K. S., Lee, W. R., Lee, H. G., Kang, D. W., Song, J. H., Hilgar, J., Rinehart, J. D., Moon, D., & Hong, C. S. (2017). Control of Interchain Antiferromagnetic Coupling in Porous Co(II)-Based Metal-Organic Frameworks by Tuning the Aromatic Linker Length: How Far Does Magnetic Interaction Propagate? Inorganic Chemistry, 56(13), 7443-7448. https://doi.org/10.1021/acs.inorgchem.7b00899

Lim, KS, Lee, WR, Lee, HG, Kang, DW, Song, JH, Hilgar, J, Rinehart, JD, Moon, D & Hong, CS 2017, 'Control of Interchain Antiferromagnetic Coupling in Porous Co(II)-Based Metal-Organic Frameworks by Tuning the Aromatic Linker Length: How Far Does Magnetic Interaction Propagate?', Inorganic Chemistry, vol. 56, no. 13, pp. 7443-7448. https://doi.org/10.1021/acs.inorgchem.7b00899

@article{23694ac255324e04a47778cf5833acb1,

title = "Control of Interchain Antiferromagnetic Coupling in Porous Co(II)-Based Metal-Organic Frameworks by Tuning the Aromatic Linker Length: How Far Does Magnetic Interaction Propagate?",

abstract = "Three MOF-74-type Co(II) frameworks with one-dimensional hexagonal channels have been prepared. Co(II) spins in a chain are ferromagnetically coupled through carboxylate and phenoxide bridges. Interchain antiferromagnetic couplings via aromatic ring pathways operate over a Co-Co length shorter than ?10.9 {\AA}, resulting in a field-induced metamagnetic transition, while being absent over lengths longer than ?14.7 {\AA}.",

author = "Lim, {Kwang Soo} and Lee, {Woo Ram} and Lee, {Han Geul} and Kang, {Dong Won} and Song, {Jeong Hwa} and Jeremy Hilgar and Rinehart, {Jeffrey D.} and Dohyun Moon and Hong, {Chang Seop}",

year = "2017",

month = jul,

day = "3",

doi = "10.1021/acs.inorgchem.7b00899",

language = "English",

volume = "56",

pages = "7443--7448",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "13",

}

TY - JOUR

T1 - Control of Interchain Antiferromagnetic Coupling in Porous Co(II)-Based Metal-Organic Frameworks by Tuning the Aromatic Linker Length

T2 - How Far Does Magnetic Interaction Propagate?

AU - Lim, Kwang Soo

AU - Lee, Woo Ram

AU - Lee, Han Geul

AU - Kang, Dong Won

AU - Song, Jeong Hwa

AU - Hilgar, Jeremy

AU - Rinehart, Jeffrey D.

AU - Moon, Dohyun

AU - Hong, Chang Seop

PY - 2017/7/3

Y1 - 2017/7/3

N2 - Three MOF-74-type Co(II) frameworks with one-dimensional hexagonal channels have been prepared. Co(II) spins in a chain are ferromagnetically coupled through carboxylate and phenoxide bridges. Interchain antiferromagnetic couplings via aromatic ring pathways operate over a Co-Co length shorter than ?10.9 Å, resulting in a field-induced metamagnetic transition, while being absent over lengths longer than ?14.7 Å.

AB - Three MOF-74-type Co(II) frameworks with one-dimensional hexagonal channels have been prepared. Co(II) spins in a chain are ferromagnetically coupled through carboxylate and phenoxide bridges. Interchain antiferromagnetic couplings via aromatic ring pathways operate over a Co-Co length shorter than ?10.9 Å, resulting in a field-induced metamagnetic transition, while being absent over lengths longer than ?14.7 Å.

UR - http://www.scopus.com/inward/record.url?scp=85021894730&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85021894730&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.7b00899

DO - 10.1021/acs.inorgchem.7b00899

M3 - Article

C2 - 28617591

AN - SCOPUS:85021894730

SN - 0020-1669

VL - 56

SP - 7443

EP - 7448

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 13

ER -

Control of Interchain Antiferromagnetic Coupling in Porous Co(II)-Based Metal-Organic Frameworks by Tuning the Aromatic Linker Length: How Far Does Magnetic Interaction Propagate?

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this