Control of the Metal Composition in Bimetallic Mg/Zn(dobpdc) Constructed from a One-Dimensional Zn-Based Template

Hyojin Kim, Hwa Young Lee, Dong Won Kang, Minjung Kang, Jong Hyeak Choe, Woo Ram Lee, Chang Seop Hong

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)


While mixed-metal ions into a single framework can be randomly arranged in most reported cases, it is synthetically challenging to control and organize the distribution of different metal ions over a three-dimensional structure. In this context, for the family of M2(dobpdc) with broad applications, we present the first case of a bimetallic Mg/Zn(dobpdc) framework with a 1:1 compositional ratio, based on a one-dimensional Zn(H2dobpdc) template, which would not be obtained by the conventional reaction of the corresponding metal salts. Moreover, we demonstrate that the resultant compositional ratios in the bimetallic M′/Zn(dobpdc) (M′ = Mg, Mn, Co, Ni) are governed by the ionic radii of the metals and the affinity of the metal ions for the linker groups. Notably, the unexpected gradual reduction in the adsorption enthalpy and the mixed CO2 adsorption feature are revealed in Mg/Zn(dobpdc) and its diamine-grafted framework, respectively.

Original languageEnglish
Pages (from-to)14107-14111
Number of pages5
JournalInorganic Chemistry
Issue number20
Publication statusPublished - 2019 Oct 21

Bibliographical note

Funding Information:
This work was supported by the Korea CCS R&D Center (KCRC) grant funded by the Korean government (the Ministry of Science, ICT and Future Planning; Grant NRF-2012-0008901), Basic Science Research Program (Grant NRF-2018R1A2A1A05079297), Priority Research Centers Program (Grant NRF-2019R1A6A1A11044070), National Research Council of Science & Technology grant by the Korea government (Grant CRC-14-1-KRICT), and PAL.

Publisher Copyright:
Copyright © 2019 American Chemical Society.

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry


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