Cost-Effective, High-Performance Porous-Organic-Polymer Conductors Functionalized with Sulfonic Acid Groups by Direct Postsynthetic Substitution

Dong Won Kang; Kwang Soo Lim; Kyung Jin Lee; Jong Hyeon Lee; Woo Ram Lee; Jeong Hwa Song; Kyu Hyun Yeom; Jin Young Kim; Chang Seop Hong

doi:10.1002/anie.201609049

Cost-Effective, High-Performance Porous-Organic-Polymer Conductors Functionalized with Sulfonic Acid Groups by Direct Postsynthetic Substitution

Dong Won Kang
, Kwang Soo Lim
, Kyung Jin Lee
, Jong Hyeon Lee
, Woo Ram Lee
, Jeong Hwa Song
, Kyu Hyun Yeom
, Jin Young Kim
, Chang Seop Hong^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

83 Citations (Scopus)

Abstract

We demonstrate the facile microwave-assisted synthesis of a porous organic framework 1 and the sulfonated solid (1S) through postsubstitution. Remarkably, the conductivity of 1S showed an approximately 300-fold enhancement at 30 °C as compared to that of 1, and reached 7.72×10⁻²S cm⁻¹at 80 °C and 90 % relative humidity. The superprotonic conductivity exceeds that observed for any conductive porous organic polymer reported to date. This material, which is cost-effective and scalable for mass production, also revealed long-term performance over more than 3 months without conductivity decay.

Original language	English
Pages (from-to)	16123-16126
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	55
Issue number	52
DOIs	https://doi.org/10.1002/anie.201609049
Publication status	Published - 2016 Dec 23

Bibliographical note

Publisher Copyright:
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Keywords

long-term performance
microwave chemistry
porous organic polymers
postsynthetic substitution
proton-conducting materials

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201609049

Cite this

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title = "Cost-Effective, High-Performance Porous-Organic-Polymer Conductors Functionalized with Sulfonic Acid Groups by Direct Postsynthetic Substitution",

abstract = "We demonstrate the facile microwave-assisted synthesis of a porous organic framework 1 and the sulfonated solid (1S) through postsubstitution. Remarkably, the conductivity of 1S showed an approximately 300-fold enhancement at 30 °C as compared to that of 1, and reached 7.72×10−2S cm−1at 80 °C and 90 \% relative humidity. The superprotonic conductivity exceeds that observed for any conductive porous organic polymer reported to date. This material, which is cost-effective and scalable for mass production, also revealed long-term performance over more than 3 months without conductivity decay.",

keywords = "long-term performance, microwave chemistry, porous organic polymers, postsynthetic substitution, proton-conducting materials",

author = "Kang, \{Dong Won\} and Lim, \{Kwang Soo\} and Lee, \{Kyung Jin\} and Lee, \{Jong Hyeon\} and Lee, \{Woo Ram\} and Song, \{Jeong Hwa\} and Yeom, \{Kyu Hyun\} and Kim, \{Jin Young\} and Hong, \{Chang Seop\}",

note = "Publisher Copyright: {\textcopyright} 2016 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2016",

month = dec,

day = "23",

doi = "10.1002/anie.201609049",

language = "English",

volume = "55",

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journal = "Angewandte Chemie - International Edition",

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T1 - Cost-Effective, High-Performance Porous-Organic-Polymer Conductors Functionalized with Sulfonic Acid Groups by Direct Postsynthetic Substitution

AU - Kang, Dong Won

AU - Lim, Kwang Soo

AU - Lee, Kyung Jin

AU - Lee, Jong Hyeon

AU - Lee, Woo Ram

AU - Song, Jeong Hwa

AU - Yeom, Kyu Hyun

AU - Kim, Jin Young

AU - Hong, Chang Seop

PY - 2016/12/23

Y1 - 2016/12/23

N2 - We demonstrate the facile microwave-assisted synthesis of a porous organic framework 1 and the sulfonated solid (1S) through postsubstitution. Remarkably, the conductivity of 1S showed an approximately 300-fold enhancement at 30 °C as compared to that of 1, and reached 7.72×10−2S cm−1at 80 °C and 90 % relative humidity. The superprotonic conductivity exceeds that observed for any conductive porous organic polymer reported to date. This material, which is cost-effective and scalable for mass production, also revealed long-term performance over more than 3 months without conductivity decay.

AB - We demonstrate the facile microwave-assisted synthesis of a porous organic framework 1 and the sulfonated solid (1S) through postsubstitution. Remarkably, the conductivity of 1S showed an approximately 300-fold enhancement at 30 °C as compared to that of 1, and reached 7.72×10−2S cm−1at 80 °C and 90 % relative humidity. The superprotonic conductivity exceeds that observed for any conductive porous organic polymer reported to date. This material, which is cost-effective and scalable for mass production, also revealed long-term performance over more than 3 months without conductivity decay.

KW - long-term performance

KW - microwave chemistry

KW - porous organic polymers

KW - postsynthetic substitution

KW - proton-conducting materials

UR - https://www.scopus.com/pages/publications/85005765018

U2 - 10.1002/anie.201609049

DO - 10.1002/anie.201609049

M3 - Article

AN - SCOPUS:85005765018

SN - 1433-7851

VL - 55

SP - 16123

EP - 16126

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 52

ER -

Cost-Effective, High-Performance Porous-Organic-Polymer Conductors Functionalized with Sulfonic Acid Groups by Direct Postsynthetic Substitution

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

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