Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter

Young Kwan Park; Beom Choi Sang; Hyunuk Kim; Kimoon Kim; Byoung Ho Won; Kihang Choi; Jung Sik Choi; Wha Seung Ahn; Nayoun Won; Sungjee Kim; Hyun Jung Dong; Seung Hoon Choi; Ghyung Hwa Kim; Sun Shin Cha; Ho Jhon Young; Kuk Yang Jin; Jaheon Kim

doi:10.1002/anie.200702324

Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter

Young Kwan Park^*
, Beom Choi Sang
, Hyunuk Kim
, Kimoon Kim
, Byoung Ho Won
, Kihang Choi
, Jung Sik Choi
, Wha Seung Ahn
, Nayoun Won
, Sungjee Kim
, Hyun Jung Dong
, Seung Hoon Choi
, Ghyung Hwa Kim
, Sun Shin Cha
, Ho Jhon Young
, Kuk Yang Jin
, Jaheon Kim

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

318 Citations (Scopus)

Abstract

(Figure Presented) Supersized pores: A new mesoporous metal-organic framework that is mainly composed of Tb³⁺ ions and tripodal carboxylate ligands has cages of 3.9 and 4.7 nm in diameter (see picture). The evacuated framework is robust and can accommodate gases or ferrocene molecules, as verified by gas-sorption measurements and luminescence studies.

Original language	English
Pages (from-to)	8230-8233
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	43
DOIs	https://doi.org/10.1002/anie.200702324
Publication status	Published - 2007

Keywords

Adsorption
Luminescence
Mesoporous materials
Metal-organic frameworks
Terbium

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200702324

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Park, Y. K., Sang, B. C., Kim, H., Kim, K., Won, B. H., Choi, K., Choi, J. S., Ahn, W. S., Won, N., Kim, S., Dong, H. J., Choi, S. H., Kim, G. H., Cha, S. S., Young, H. J., Jin, K. Y., & Kim, J. (2007). Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter. Angewandte Chemie - International Edition, 46(43), 8230-8233. https://doi.org/10.1002/anie.200702324

Park, YK, Sang, BC, Kim, H, Kim, K, Won, BH, Choi, K, Choi, JS, Ahn, WS, Won, N, Kim, S, Dong, HJ, Choi, SH, Kim, GH, Cha, SS, Young, HJ, Jin, KY & Kim, J 2007, 'Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter', Angewandte Chemie - International Edition, vol. 46, no. 43, pp. 8230-8233. https://doi.org/10.1002/anie.200702324

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title = "Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter",

abstract = "(Figure Presented) Supersized pores: A new mesoporous metal-organic framework that is mainly composed of Tb3+ ions and tripodal carboxylate ligands has cages of 3.9 and 4.7 nm in diameter (see picture). The evacuated framework is robust and can accommodate gases or ferrocene molecules, as verified by gas-sorption measurements and luminescence studies.",

keywords = "Adsorption, Luminescence, Mesoporous materials, Metal-organic frameworks, Terbium",

author = "Park, \{Young Kwan\} and Sang, \{Beom Choi\} and Hyunuk Kim and Kimoon Kim and Won, \{Byoung Ho\} and Kihang Choi and Choi, \{Jung Sik\} and Ahn, \{Wha Seung\} and Nayoun Won and Sungjee Kim and Dong, \{Hyun Jung\} and Choi, \{Seung Hoon\} and Kim, \{Ghyung Hwa\} and Cha, \{Sun Shin\} and Young, \{Ho Jhon\} and Jin, \{Kuk Yang\} and Jaheon Kim",

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doi = "10.1002/anie.200702324",

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AU - Park, Young Kwan

AU - Sang, Beom Choi

AU - Kim, Hyunuk

AU - Kim, Kimoon

AU - Won, Byoung Ho

AU - Choi, Kihang

AU - Choi, Jung Sik

AU - Ahn, Wha Seung

AU - Won, Nayoun

AU - Kim, Sungjee

AU - Dong, Hyun Jung

AU - Choi, Seung Hoon

AU - Kim, Ghyung Hwa

AU - Cha, Sun Shin

AU - Young, Ho Jhon

AU - Jin, Kuk Yang

AU - Kim, Jaheon

PY - 2007

Y1 - 2007

N2 - (Figure Presented) Supersized pores: A new mesoporous metal-organic framework that is mainly composed of Tb3+ ions and tripodal carboxylate ligands has cages of 3.9 and 4.7 nm in diameter (see picture). The evacuated framework is robust and can accommodate gases or ferrocene molecules, as verified by gas-sorption measurements and luminescence studies.

AB - (Figure Presented) Supersized pores: A new mesoporous metal-organic framework that is mainly composed of Tb3+ ions and tripodal carboxylate ligands has cages of 3.9 and 4.7 nm in diameter (see picture). The evacuated framework is robust and can accommodate gases or ferrocene molecules, as verified by gas-sorption measurements and luminescence studies.

KW - Adsorption

KW - Luminescence

KW - Mesoporous materials

KW - Metal-organic frameworks

KW - Terbium

UR - https://www.scopus.com/pages/publications/36048944712

U2 - 10.1002/anie.200702324

DO - 10.1002/anie.200702324

M3 - Article

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AN - SCOPUS:36048944712

SN - 1433-7851

VL - 46

SP - 8230

EP - 8233

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 43

ER -

Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter

Abstract

Keywords

ASJC Scopus subject areas

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