Cyanide-bridged feiii-mniii bimetallic complexes with dimeric and chain structures constructed from a newly made mer-fe tricyanide: structures and magnetic properties

Jae Il Kim; Hyun Young Kwak; Jung Hee Yoon; Dae Won Ryu; In Young Yoo; Namgeun Yang; Beong Ki Cho; Je Geun Park; Hyosug Lee; Chang Seop Hong

doi:10.1021/ic802033q

Cyanide-bridged feiii-mniii bimetallic complexes with dimeric and chain structures constructed from a newly made mer-fe tricyanide: structures and magnetic properties

Jae Il Kim, Hyun Young Kwak, Jung Hee Yoon, Dae Won Ryu, In Young Yoo, Namgeun Yang, Beong Ki Cho, Je Geun Park, Hyosug Lee, Chang Seop Hong

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

73 Citations (Scopus)

Abstract

Four cyanide-linked Fe^III-Mn^III complexes were prepared by reacting Mn Schiff bases with a new molecular precursor (PPh ₄)[Fe(qcq)(CN)₃] [1; qcq ) 8-(2-quinolinecarboxamido) quinoline anion]. They include a dimeric molecule, [Fe(qcq)(CN) ₃][Mn(3-MeOsalen)(H₂O)] · 2H₂O [2· 2H₂O; 3-MeOsalen ) N,N′-ethylenebis(3- methoxysalicylideneiminato) dianion], and three 1D zigzag chains, [Fe(qcq)(CN)3][Mn(5-Clsalen)] · 3H₂O [3 · 2MeOH; 5-Clsalen ) N,N'- ethylenebis(5-chlorosalicylideneiminato) dianion], [Fe(qcq)(CN)₃][Mn(5-Brsalen)] · 2MeOH [4 · 2MeOH; 5-Brsalen ) N,N′-ethylenebis(5-bromosalicylideneiminato) dianion], and Fe(qcq)(CN)₃][Mn(salen)] · MeCN ·H₂O [5 · MeCN; salen ) N,N′-ethylenebis(salicylideneiminato) dianion]. The complexes consist of extensive hydrogen bonding and π-π stacking interactions, generating multidimensional structures. Magnetic studies demonstrate that antiferromagnetic couplings are operative between FeIII and MnIII centers bridged by cyanide ligands. On the basis of an infinite chain model, magnetic coupling parameters of 2-5 range from -9.3 to -14.1 cm ^-1. A long-range order is observed at 2.3 K for 3 and 2.2 K for 4, while compound 5 shows spin glass behavior possibly coupled with magnetic ordering.

Original language	English
Pages (from-to)	2956-2966
Number of pages	11
Journal	Inorganic Chemistry
Volume	48
Issue number	7
DOIs	https://doi.org/10.1021/ic802033q
Publication status	Published - 2009

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic802033q

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@article{3aaf261ec78b465496e1d651d6872449,

title = "Cyanide-bridged feiii-mniii bimetallic complexes with dimeric and chain structures constructed from a newly made mer-fe tricyanide: structures and magnetic properties",

abstract = "Four cyanide-linked FeIII-MnIII complexes were prepared by reacting Mn Schiff bases with a new molecular precursor (PPh 4)[Fe(qcq)(CN)3] [1; qcq ) 8-(2-quinolinecarboxamido) quinoline anion]. They include a dimeric molecule, [Fe(qcq)(CN) 3][Mn(3-MeOsalen)(H2O)] · 2H2O [2· 2H2O; 3-MeOsalen ) N,N′-ethylenebis(3- methoxysalicylideneiminato) dianion], and three 1D zigzag chains, [Fe(qcq)(CN)3][Mn(5-Clsalen)] · 3H2O [3 · 2MeOH; 5-Clsalen ) N,N'- ethylenebis(5-chlorosalicylideneiminato) dianion], [Fe(qcq)(CN)3][Mn(5-Brsalen)] · 2MeOH [4 · 2MeOH; 5-Brsalen ) N,N′-ethylenebis(5-bromosalicylideneiminato) dianion], and Fe(qcq)(CN)3][Mn(salen)] · MeCN ·H2O [5 · MeCN; salen ) N,N′-ethylenebis(salicylideneiminato) dianion]. The complexes consist of extensive hydrogen bonding and π-π stacking interactions, generating multidimensional structures. Magnetic studies demonstrate that antiferromagnetic couplings are operative between FeIII and MnIII centers bridged by cyanide ligands. On the basis of an infinite chain model, magnetic coupling parameters of 2-5 range from -9.3 to -14.1 cm -1. A long-range order is observed at 2.3 K for 3 and 2.2 K for 4, while compound 5 shows spin glass behavior possibly coupled with magnetic ordering.",

author = "Kim, {Jae Il} and Kwak, {Hyun Young} and Yoon, {Jung Hee} and Ryu, {Dae Won} and Yoo, {In Young} and Namgeun Yang and Cho, {Beong Ki} and Park, {Je Geun} and Hyosug Lee and Hong, {Chang Seop}",

year = "2009",

doi = "10.1021/ic802033q",

language = "English",

volume = "48",

pages = "2956--2966",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "7",

}

TY - JOUR

T1 - Cyanide-bridged feiii-mniii bimetallic complexes with dimeric and chain structures constructed from a newly made mer-fe tricyanide

T2 - structures and magnetic properties

AU - Kim, Jae Il

AU - Kwak, Hyun Young

AU - Yoon, Jung Hee

AU - Ryu, Dae Won

AU - Yoo, In Young

AU - Yang, Namgeun

AU - Cho, Beong Ki

AU - Park, Je Geun

AU - Lee, Hyosug

AU - Hong, Chang Seop

PY - 2009

Y1 - 2009

N2 - Four cyanide-linked FeIII-MnIII complexes were prepared by reacting Mn Schiff bases with a new molecular precursor (PPh 4)[Fe(qcq)(CN)3] [1; qcq ) 8-(2-quinolinecarboxamido) quinoline anion]. They include a dimeric molecule, [Fe(qcq)(CN) 3][Mn(3-MeOsalen)(H2O)] · 2H2O [2· 2H2O; 3-MeOsalen ) N,N′-ethylenebis(3- methoxysalicylideneiminato) dianion], and three 1D zigzag chains, [Fe(qcq)(CN)3][Mn(5-Clsalen)] · 3H2O [3 · 2MeOH; 5-Clsalen ) N,N'- ethylenebis(5-chlorosalicylideneiminato) dianion], [Fe(qcq)(CN)3][Mn(5-Brsalen)] · 2MeOH [4 · 2MeOH; 5-Brsalen ) N,N′-ethylenebis(5-bromosalicylideneiminato) dianion], and Fe(qcq)(CN)3][Mn(salen)] · MeCN ·H2O [5 · MeCN; salen ) N,N′-ethylenebis(salicylideneiminato) dianion]. The complexes consist of extensive hydrogen bonding and π-π stacking interactions, generating multidimensional structures. Magnetic studies demonstrate that antiferromagnetic couplings are operative between FeIII and MnIII centers bridged by cyanide ligands. On the basis of an infinite chain model, magnetic coupling parameters of 2-5 range from -9.3 to -14.1 cm -1. A long-range order is observed at 2.3 K for 3 and 2.2 K for 4, while compound 5 shows spin glass behavior possibly coupled with magnetic ordering.

AB - Four cyanide-linked FeIII-MnIII complexes were prepared by reacting Mn Schiff bases with a new molecular precursor (PPh 4)[Fe(qcq)(CN)3] [1; qcq ) 8-(2-quinolinecarboxamido) quinoline anion]. They include a dimeric molecule, [Fe(qcq)(CN) 3][Mn(3-MeOsalen)(H2O)] · 2H2O [2· 2H2O; 3-MeOsalen ) N,N′-ethylenebis(3- methoxysalicylideneiminato) dianion], and three 1D zigzag chains, [Fe(qcq)(CN)3][Mn(5-Clsalen)] · 3H2O [3 · 2MeOH; 5-Clsalen ) N,N'- ethylenebis(5-chlorosalicylideneiminato) dianion], [Fe(qcq)(CN)3][Mn(5-Brsalen)] · 2MeOH [4 · 2MeOH; 5-Brsalen ) N,N′-ethylenebis(5-bromosalicylideneiminato) dianion], and Fe(qcq)(CN)3][Mn(salen)] · MeCN ·H2O [5 · MeCN; salen ) N,N′-ethylenebis(salicylideneiminato) dianion]. The complexes consist of extensive hydrogen bonding and π-π stacking interactions, generating multidimensional structures. Magnetic studies demonstrate that antiferromagnetic couplings are operative between FeIII and MnIII centers bridged by cyanide ligands. On the basis of an infinite chain model, magnetic coupling parameters of 2-5 range from -9.3 to -14.1 cm -1. A long-range order is observed at 2.3 K for 3 and 2.2 K for 4, while compound 5 shows spin glass behavior possibly coupled with magnetic ordering.

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U2 - 10.1021/ic802033q

DO - 10.1021/ic802033q

M3 - Article

C2 - 19249870

AN - SCOPUS:64349095394

SN - 0020-1669

VL - 48

SP - 2956

EP - 2966

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 7

ER -

Cyanide-bridged feiii-mniii bimetallic complexes with dimeric and chain structures constructed from a newly made mer-fe tricyanide: structures and magnetic properties

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