Cyanide-bridged one-dimensional ferromagnetic RuIIIMn III coordination polymer exhibiting a field-induced magnetic phase transition

Jung Hee Yoon; Houng Sik Yoo; Hyoung Chan Kim; Sung Won Yoon; Byoung Jin Suh; Chang Seop Hong

doi:10.1021/ic802186z

Cyanide-bridged one-dimensional ferromagnetic Ru^IIIMn ^III coordination polymer exhibiting a field-induced magnetic phase transition

Jung Hee Yoon, Houng Sik Yoo, Hyoung Chan Kim, Sung Won Yoon, Byoung Jin Suh, Chang Seop Hong

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

A cyanide-linked Ru^III(4d)-Mn^III(3d) bimetallic chain complex (1) was prepared by the self-assembly of a ruthenium(III) bicyanide and a Mn^III Schiff base. Ferromagnetic couplings between the magnetic centers are present within a chain, while antiferromagnetic interactions between chains (T_N = 2.5 K) transmit. Complex 1 also shows a field-induced magnetic phase transition.

Original language	English
Pages (from-to)	816-818
Number of pages	3
Journal	Inorganic Chemistry
Volume	48
Issue number	3
DOIs	https://doi.org/10.1021/ic802186z
Publication status	Published - 2009 Feb 2

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic802186z

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abstract = "A cyanide-linked RuIII(4d)-MnIII(3d) bimetallic chain complex (1) was prepared by the self-assembly of a ruthenium(III) bicyanide and a MnIII Schiff base. Ferromagnetic couplings between the magnetic centers are present within a chain, while antiferromagnetic interactions between chains (TN = 2.5 K) transmit. Complex 1 also shows a field-induced magnetic phase transition.",

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AU - Yoon, Jung Hee

AU - Yoo, Houng Sik

AU - Kim, Hyoung Chan

AU - Yoon, Sung Won

AU - Suh, Byoung Jin

AU - Hong, Chang Seop

PY - 2009/2/2

Y1 - 2009/2/2

N2 - A cyanide-linked RuIII(4d)-MnIII(3d) bimetallic chain complex (1) was prepared by the self-assembly of a ruthenium(III) bicyanide and a MnIII Schiff base. Ferromagnetic couplings between the magnetic centers are present within a chain, while antiferromagnetic interactions between chains (TN = 2.5 K) transmit. Complex 1 also shows a field-induced magnetic phase transition.

AB - A cyanide-linked RuIII(4d)-MnIII(3d) bimetallic chain complex (1) was prepared by the self-assembly of a ruthenium(III) bicyanide and a MnIII Schiff base. Ferromagnetic couplings between the magnetic centers are present within a chain, while antiferromagnetic interactions between chains (TN = 2.5 K) transmit. Complex 1 also shows a field-induced magnetic phase transition.

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Cyanide-bridged one-dimensional ferromagnetic Ru^IIIMn ^III coordination polymer exhibiting a field-induced magnetic phase transition

Abstract

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