Cyanide-bridged W VMn III single-chain magnet based on an octacoordinate [W(CN) 6(phen)] - anion

Jinwuk Lee; Kwangsoo Lim; Junghee Yoon; Daewon Ryu; Bongho Koo; Euikwan Koh; Changseop Hong

doi:10.1007/s11426-012-4539-4

Cyanide-bridged W ^VMn ^III single-chain magnet based on an octacoordinate [W(CN) ₆(phen)] ^- anion

Jinwuk Lee, Kwangsoo Lim, Junghee Yoon, Daewon Ryu, Bongho Koo, Euikwan Koh, Changseop Hong^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Reaction of unique [W(CN) ₆(phen) ^- with a magnetically anisotropic Mn Schiff base yielded a W ^V(5d)-Mn ^III(3d) bimetallic compound with a linear chain structure. The magnetic properties of the chain complex feature a ferrimagnetic behavior as well as slow magnetic relaxation typical for a single-chain magnet.

Original language	English
Pages (from-to)	1012-1017
Number of pages	6
Journal	Science China Chemistry
Volume	55
Issue number	6
DOIs	https://doi.org/10.1007/s11426-012-4539-4
Publication status	Published - 2012 Jun

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation of Korea Funded by the Korean Government (2011-0003264) and by the Priority Research Centers Program through the National Research Foundation of Korea (NRF) Funded by the Ministry of Education, Science and Technology (NRF20110018396).

Keywords

crystal structure
cyanide
manganese
single-chain magnet
tungsten

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1007/s11426-012-4539-4

Cite this

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title = "Cyanide-bridged W VMn III single-chain magnet based on an octacoordinate [W(CN) 6(phen)] - anion",

abstract = "Reaction of unique [W(CN) 6(phen) - with a magnetically anisotropic Mn Schiff base yielded a W V(5d)-Mn III(3d) bimetallic compound with a linear chain structure. The magnetic properties of the chain complex feature a ferrimagnetic behavior as well as slow magnetic relaxation typical for a single-chain magnet.",

keywords = "crystal structure, cyanide, manganese, single-chain magnet, tungsten",

author = "Jinwuk Lee and Kwangsoo Lim and Junghee Yoon and Daewon Ryu and Bongho Koo and Euikwan Koh and Changseop Hong",

note = "Funding Information: This work was supported by the National Research Foundation of Korea Funded by the Korean Government (2011-0003264) and by the Priority Research Centers Program through the National Research Foundation of Korea (NRF) Funded by the Ministry of Education, Science and Technology (NRF20110018396).",

year = "2012",

month = jun,

doi = "10.1007/s11426-012-4539-4",

language = "English",

volume = "55",

pages = "1012--1017",

journal = "Science China Chemistry",

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publisher = "Science China Press",

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TY - JOUR

T1 - Cyanide-bridged W VMn III single-chain magnet based on an octacoordinate [W(CN) 6(phen)] - anion

AU - Lee, Jinwuk

AU - Lim, Kwangsoo

AU - Yoon, Junghee

AU - Ryu, Daewon

AU - Koo, Bongho

AU - Koh, Euikwan

AU - Hong, Changseop

N1 - Funding Information: This work was supported by the National Research Foundation of Korea Funded by the Korean Government (2011-0003264) and by the Priority Research Centers Program through the National Research Foundation of Korea (NRF) Funded by the Ministry of Education, Science and Technology (NRF20110018396).

PY - 2012/6

Y1 - 2012/6

N2 - Reaction of unique [W(CN) 6(phen) - with a magnetically anisotropic Mn Schiff base yielded a W V(5d)-Mn III(3d) bimetallic compound with a linear chain structure. The magnetic properties of the chain complex feature a ferrimagnetic behavior as well as slow magnetic relaxation typical for a single-chain magnet.

AB - Reaction of unique [W(CN) 6(phen) - with a magnetically anisotropic Mn Schiff base yielded a W V(5d)-Mn III(3d) bimetallic compound with a linear chain structure. The magnetic properties of the chain complex feature a ferrimagnetic behavior as well as slow magnetic relaxation typical for a single-chain magnet.

KW - crystal structure

KW - cyanide

KW - manganese

KW - single-chain magnet

KW - tungsten

UR - https://www.scopus.com/pages/publications/84862820875

U2 - 10.1007/s11426-012-4539-4

DO - 10.1007/s11426-012-4539-4

M3 - Article

AN - SCOPUS:84862820875

SN - 1674-7291

VL - 55

SP - 1012

EP - 1017

JO - Science China Chemistry

JF - Science China Chemistry

IS - 6

ER -