Development of Crosslinked PEI Solid Adsorbents for CO2 Capture

Sunbin Jeon, Hyunchul Jung, Dong Hyun Jo, Sung Hyun Kim

Research output: Contribution to journalConference articlepeer-review

16 Citations (Scopus)

Abstract

Impregnated amine adsorbents show high CO2 adsorption capacity, however, leaching out and evaporation of amines, urea formation problem was existed. These problems are critical to the long term operation of CO2 capture, and related to the physical and chemical stability of amines at regeneration temperature. In order to overcome limitations, crosslinking method between amine groups was introduced. Crosslinkers having two amine reactive groups, such as acid, aldehyde were used to prepare crosslinked polyethyleneimine (PEI)-impregnated adsorbents. The viscosities of the crosslinked PEIs were increased compared to the pristine PEI. The structure and the amine ratio of the crosslinked PEIs were investigated by 13C NMR analysis. Simulated TSA cyclic operation was conducted by thermogravimetric analyzer (TGA), and all of crosslinked PEI-impregnated adsorbents were exhibited lower CO2 capacity compared to PEI-impregnated adsorbents, but less urea formation was observed.

Original languageEnglish
Pages (from-to)2287-2293
Number of pages7
JournalEnergy Procedia
Volume114
DOIs
Publication statusPublished - 2017
Event13th International Conference on Greenhouse Gas Control Technologies, GHGT 2016 - Lausanne, Switzerland
Duration: 2016 Nov 142016 Nov 18

Bibliographical note

Funding Information:
This work was supported by the Korea CCS R&D Center (KCRC) grant funded by the Korea government (Ministry of Science, ICT & Future Planning) (No. NRF-2014M1A8A1049251).

Publisher Copyright:
© 2017 The Authors.

Copyright:
Copyright 2017 Elsevier B.V., All rights reserved.

Keywords

  • CO adsorption
  • MSU-F
  • crosslink
  • polyethyleneimine

ASJC Scopus subject areas

  • General Energy

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