Development of heterogeneous catalyst system for esterification of free fatty acid contained in used vegetable oil

Hak Ju Kim, Bo Seung Kang, Min Ju Kim, Deog Keun Kim, Jin Suck Lee, Kwan Young Lee

    Research output: Contribution to journalArticlepeer-review

    25 Citations (Scopus)

    Abstract

    Biodiesel produced by the transesterification of vegetable oils (VOs) is a promising alternative fuel to diesel which can overcome limited fossil fuel resources and environmental concern. In this work, an environmentally benign process for the production of biodiesel from used VOs by heterogeneous catalyst has been developed. Free fatty acids contained in used VOs, which cause several severe problems for the transesterification catalyzed by base catalyst, were converted to fatty acid methyl esters (FAME). The activity of several heterogeneous acid catalysts was investigated. Sulfated zirconia showed the highest activity among them. The optimization of the reaction conditions was also carried out.

    Original languageEnglish
    Pages (from-to)201-204
    Number of pages4
    JournalStudies in Surface Science and Catalysis
    Volume153
    DOIs
    Publication statusPublished - 2004

    Bibliographical note

    Funding Information:
    Financial support by the Grant-in-aid from the Industrial Waste Recycling R&D Center and the Ministry of Science and Technology is highly appreciated. The authors also appreciate the support by research grants from the Korea Science and Engineering Foundation (KOSEF) through the Applied Rheology Center (ARC) at Korea University.

    ASJC Scopus subject areas

    • Catalysis
    • Condensed Matter Physics
    • Physical and Theoretical Chemistry
    • Surfaces, Coatings and Films
    • Materials Chemistry

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