Distinct critical fluctuations and molecular motions manifest in a model biomembrane

Kyu Won Lee, Cheol Eui Lee, J. Y. Choi, Joon Kim

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

Lattice dynamics in bis-(n-C16H37NH 3)SnCl6, where the hydrocarbon part is analogous to lipid membrane, was investigated by means of 200 MHz 1H nuclear magnetic resonance. As a result, critical fluctuations and molecular dynamics associated with the phase transitions, an order-disorder and a conformational phase transition, were distinguished in a wide temperature range. The dynamical origin of the critical fluctuations, observed in the long-chain compounds but not in the short-chain compounds, by the laboratory frame spin-lattice relaxation measurements, is revealed and discussed in this work.

Original languageEnglish
Pages (from-to)83-88
Number of pages6
JournalSolid State Communications
Volume133
Issue number2
DOIs
Publication statusPublished - 2005 Jan

Bibliographical note

Funding Information:
This work was supported by the KISTEP (National Research Laboratory and M102KS010001-02K1901-01814) and by the Korea Research foundation (Brain Korea 21 Project in 2004 and Grant No. C00060). Measurements at the Korea Basic Science Institute (KBSI) are acknowledged.

Keywords

  • D. Phase transition
  • E. Nuclear magnetic resonances

ASJC Scopus subject areas

  • General Chemistry
  • Condensed Matter Physics
  • Materials Chemistry

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