Disulfides as mercapto-precursors in nucleophilic ring opening reaction of polymeric epoxides: Establishing equimolar stoichiometric conditions in a thiol-epoxy 'click' reaction

Keyphrases

• Disulfide 100%
• Epoxides 100%
• Mercapto 100%
• Thiol-epoxy Click Reaction 100%
• Nucleophilic Ring-opening Reactions 100%
• Stoichiometric Conditions 100%
• Click Reaction 66%
• Nucleophile 66%
• Commercially Available 33%
• Stoichiometry 33%
• Sodium Borohydride 33%
• Thiols 33%
• Disulfide Bond 33%
• In Situ 33%
• Ambient Conditions 33%
• Ring-opening Reaction 33%
• Thiolate 33%
• Sulfhydryl 33%
• Oxidation Mechanism 33%
• S-S Bond 33%
• Thiol Compounds 33%
• Depolymerization 33%
• Free Thiols 33%
• Polymer Synthesis 33%
• Side Reactions 33%
• Epoxy Polymer 33%
• Activation Strategy 33%
• Base Hydrolysis 33%
• Glycidyl 33%
• Oxirane Ring Opening 33%
• Oxidative Dimerization 33%
• Post-synthetic Functionalization 33%
• Sulfhydryl Oxidation 33%
• Thiol Precursors 33%
• Partial Consumption 33%

Chemistry

• Disulfide 100%
• Ring Opening Reaction 100%
• Epoxide 100%
• Thiol 100%
• Nucleophile 50%
• Reaction Stoichiometry 25%
• Oxidation Reaction 25%
• Base 25%
• Polymerization 25%
• Sodium Borohydride 25%
• Oxirane 25%
• Polymer Synthesis 25%
• Oxidative Dimerization 25%
• formation 25%