Divergent insertion reactions of Pt-carbenes generated from [3+2] cyclization of platinum-bound pyrylliums

Keyphrases

• Cyclization 100%
• Carbenes 100%
• Propylene 100%
• Insertion Reaction 100%
• Reaction Mixture 50%
• Double Bond 50%
• Toluene 50%
• Test Tube 50%
• Molecular Modeling 50%
• Steric Hindrance 50%
• Cycloaddition 50%
• C-H Bond 50%
• Carbene Complexes 50%
• Tetracyclic 50%
• Huisgen 50%
• Argon Atmosphere 50%
• Enynals 50%
• PtCl2 50%
• Acid-catalyzed Rearrangement 50%
• 2-Alkynylbenzaldehyde 50%
• Spiranes 50%

Chemistry

• Insertion Reaction 100%
• Carbene 100%
• Cyclopropane 66%
• Double Bond 33%
• Steric Hindrance 33%
• Argon 33%
• Hydrogen Bond 33%
• Cycloaddition 33%
• Molecular Model 33%