Dual-bed catalytic system comprising Al₂O₃ and Ba/Al₂O₃ with enhanced 1-octene productivity in 1-octanol dehydration for linear α-olefin production

To produce high-purity 1-octene, the dehydration of 1-octanol was performed over a dual-bed catalytic system comprising Al₂O₃ and Ba/Al₂O₃ catalysts. The influence of the catalyst weight on the activities of Al₂O₃ and Ba/Al₂O₃ single-bed systems was initially investigated at liquid hourly space velocities (LHSVs) of 7–168 h⁻¹ at 400 °C. For the Al₂O₃ single-bed system, the 1-octene selectivity decreased with an increase in the catalyst weight. Although the 1-octene selectivity of Ba/Al₂O₃ increased owing to the anti-Saytzeff effect, its yield was limited due to a low 1-octanol conversion. The efficiency of the dual-bed catalytic system was subsequently investigated by varying the catalyst bed ratio (i.e., xAl–yBa). The 40Al-60Ba catalytic system afforded a higher conversion (95.3%) and productivity than the Ba/Al₂O₃ single-bed system at an LHSV of 56 h⁻¹. Moreover, the 10Al-90Ba catalytic system with a high Ba/Al₂O₃ catalyst ratio exhibited a high 1-octene productivity at LHSVs of 7–28 h⁻¹, while also yielding a high-purity product. The single-bed system exhibited a lower selectivity toward 1-octene than the dual-bed system, and after 100 h, the 10Al-90Ba dual-bed system offered a stable catalytic performance regardless of the small reductions in the 1-octene selectivity and yield.