Effect of clay content, homogenization RPM, pH, and ultrasonication on mechanical and barrier properties of fish gelatin/montmorillonite nanocomposite films

Ho J. Bae; Hyun J. Park; Seung I. Hong; Young J. Byun; Duncan O. Darby; Robert M. Kimmel; William S. Whiteside

doi:10.1016/j.lwt.2008.12.016

Effect of clay content, homogenization RPM, pH, and ultrasonication on mechanical and barrier properties of fish gelatin/montmorillonite nanocomposite films

Ho J. Bae
, Hyun J. Park
, Seung I. Hong
, Young J. Byun
, Duncan O. Darby
, Robert M. Kimmel
, William S. Whiteside^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

131 Citations (Scopus)

Abstract

The effect of clay content, homogenization RPM, and pH on the mechanical and barrier properties of fish gelatin/nanoclay composite films was investigated. The addition of 5% nanoclay (w/w) increased the tensile strength from 30.31 ± 2.37 MPa to 40.71 ± 3.30 MPa. The 9 g clay/100 g gelatin film exhibited the largest improvements in oxygen and water barrier properties. Oxygen permeability decreased from 402.8 × 10^-6 ± 0.7 × 10^-6 g m/m² day atm to 114.4 × 10^-6 ± 16.2 × 10^-6 g m/m² day atm and the water vapor permeability decreased from 31.2 × 10^-3 ± 1.6 × 10^-3 ng m/m² s Pa to 8.1 × 10^-3 ± 0.1 × 10^-3 ng m/m² s Pa. The XRD and TEM observation suggested that the ultrasonication treatment (30 min at 40% output) resulted in exfoliation of the silicates.

Original language	English
Pages (from-to)	1179-1186
Number of pages	8
Journal	LWT
Volume	42
Issue number	6
DOIs	https://doi.org/10.1016/j.lwt.2008.12.016
Publication status	Published - 2009 Jul

Keywords

Biopolymer
Film
Fish gelatin
Nanoclay
Ultrasonication

ASJC Scopus subject areas

Food Science

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10.1016/j.lwt.2008.12.016

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@article{7a051a270c0d46b8be85a132e65e7cd0,

title = "Effect of clay content, homogenization RPM, pH, and ultrasonication on mechanical and barrier properties of fish gelatin/montmorillonite nanocomposite films",

abstract = "The effect of clay content, homogenization RPM, and pH on the mechanical and barrier properties of fish gelatin/nanoclay composite films was investigated. The addition of 5\% nanoclay (w/w) increased the tensile strength from 30.31 ± 2.37 MPa to 40.71 ± 3.30 MPa. The 9 g clay/100 g gelatin film exhibited the largest improvements in oxygen and water barrier properties. Oxygen permeability decreased from 402.8 × 10-6 ± 0.7 × 10-6 g m/m2 day atm to 114.4 × 10-6 ± 16.2 × 10-6 g m/m2 day atm and the water vapor permeability decreased from 31.2 × 10-3 ± 1.6 × 10-3 ng m/m2 s Pa to 8.1 × 10-3 ± 0.1 × 10-3 ng m/m2 s Pa. The XRD and TEM observation suggested that the ultrasonication treatment (30 min at 40\% output) resulted in exfoliation of the silicates.",

keywords = "Biopolymer, Film, Fish gelatin, Nanoclay, Ultrasonication",

author = "Bae, \{Ho J.\} and Park, \{Hyun J.\} and Hong, \{Seung I.\} and Byun, \{Young J.\} and Darby, \{Duncan O.\} and Kimmel, \{Robert M.\} and Whiteside, \{William S.\}",

year = "2009",

month = jul,

doi = "10.1016/j.lwt.2008.12.016",

language = "English",

volume = "42",

pages = "1179--1186",

journal = "LWT",

issn = "0023-6438",

publisher = "Academic Press",

number = "6",

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TY - JOUR

T1 - Effect of clay content, homogenization RPM, pH, and ultrasonication on mechanical and barrier properties of fish gelatin/montmorillonite nanocomposite films

AU - Bae, Ho J.

AU - Park, Hyun J.

AU - Hong, Seung I.

AU - Byun, Young J.

AU - Darby, Duncan O.

AU - Kimmel, Robert M.

AU - Whiteside, William S.

PY - 2009/7

Y1 - 2009/7

N2 - The effect of clay content, homogenization RPM, and pH on the mechanical and barrier properties of fish gelatin/nanoclay composite films was investigated. The addition of 5% nanoclay (w/w) increased the tensile strength from 30.31 ± 2.37 MPa to 40.71 ± 3.30 MPa. The 9 g clay/100 g gelatin film exhibited the largest improvements in oxygen and water barrier properties. Oxygen permeability decreased from 402.8 × 10-6 ± 0.7 × 10-6 g m/m2 day atm to 114.4 × 10-6 ± 16.2 × 10-6 g m/m2 day atm and the water vapor permeability decreased from 31.2 × 10-3 ± 1.6 × 10-3 ng m/m2 s Pa to 8.1 × 10-3 ± 0.1 × 10-3 ng m/m2 s Pa. The XRD and TEM observation suggested that the ultrasonication treatment (30 min at 40% output) resulted in exfoliation of the silicates.

AB - The effect of clay content, homogenization RPM, and pH on the mechanical and barrier properties of fish gelatin/nanoclay composite films was investigated. The addition of 5% nanoclay (w/w) increased the tensile strength from 30.31 ± 2.37 MPa to 40.71 ± 3.30 MPa. The 9 g clay/100 g gelatin film exhibited the largest improvements in oxygen and water barrier properties. Oxygen permeability decreased from 402.8 × 10-6 ± 0.7 × 10-6 g m/m2 day atm to 114.4 × 10-6 ± 16.2 × 10-6 g m/m2 day atm and the water vapor permeability decreased from 31.2 × 10-3 ± 1.6 × 10-3 ng m/m2 s Pa to 8.1 × 10-3 ± 0.1 × 10-3 ng m/m2 s Pa. The XRD and TEM observation suggested that the ultrasonication treatment (30 min at 40% output) resulted in exfoliation of the silicates.

KW - Biopolymer

KW - Film

KW - Fish gelatin

KW - Nanoclay

KW - Ultrasonication

UR - https://www.scopus.com/pages/publications/62549097703

U2 - 10.1016/j.lwt.2008.12.016

DO - 10.1016/j.lwt.2008.12.016

M3 - Article

AN - SCOPUS:62549097703

SN - 0023-6438

VL - 42

SP - 1179

EP - 1186

JO - LWT

JF - LWT

IS - 6

ER -

Effect of clay content, homogenization RPM, pH, and ultrasonication on mechanical and barrier properties of fish gelatin/montmorillonite nanocomposite films

Abstract

Keywords

ASJC Scopus subject areas

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